Results 11 to 20 of about 103,875 (262)
Effect of benzocyclobutadieno-annelation on cyclic conjugation in perylene
Earlier studies showed that the intensity of cyclic conjugation in the central ring R of perylene can be significantly altered by means of benzo-annelation. In particular, linear (resp. angular) benzoannelation was found to decrease (resp.
Ivan Gutman, Beba Stojanovska
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A set of novel 1,4-diaryl-1,3-butadiynes terminated by two 7-(arylethynyl)-1,8-bis(dimethylamino)naphthalene fragments was prepared via the Glaser–Hay oxidative dimerization of 2-ethynyl-7-(arylethynyl)-1,8-bis(dimethylamino)naphthalenes.
Semyon V. Tsybulin +4 more
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Stability of bicalicene isomers: A topological study [PDF]
Bicalicene is the conjugated hydrocarbon obtained by joining two calicene fragments. This can be done in two different ways, thus resulting in two bicalicene isomers (tentatively referred to as cis and trans).
Gutman Ivan
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Peptide-Peptide Nucleic Acid (PNA) conjugates targeting essential bacterial genes have shown significant potential in developing novel antisense antimicrobials. The majority of efforts in this area are focused on identifying different PNA targets and the
Nitin A. Patil +12 more
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Topological properties of altan-benzenoid hydrocarbons [PDF]
The main topological characteristics of altan-benzenoids are established. In particular, it is shown that the perimeter of Kekuléan altan-benzenoids is of size 4k , having a destablizing (antiaromatic) energy effect, similar to (4k)-annulenes.
Gutman Ivan
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A simple mathematical model for the effect of benzoannelation on cyclic conjugation [PDF]
In a series of earlier studies, it was established that benzoannelation in the angular (resp. linear) position relative to a ring R of a polycyclic conjugated π-electron system, increases (resp.
Gutman Ivan, Balaban Aexanru T.
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Enantioselective Conjugate Allylation of Cyclic Enones [PDF]
Enantioselective organocatalytic 1,2-allylation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture of diastereomers. This appears to be a general method for the net enantioselective conjugate allylation of cyclic enones.
Douglass F, Taber +2 more
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Within a systematic study of cyclic conjugation in the benzo-annelated derivatives of acenaphthylene and fluoranthene, a general regularity was discovered, named phenyl-cyclopentadienyl rule (PCP rule).
Jelena Đurđević, Ivan Gutman
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Expansivity and Roquette Groups [PDF]
One looks at expansive subgroups in particular examples of Roquette groups. This study is motivated by the importance of expansive subgroups in the theory of stabilizing bisets highlighted in [BouThe].
Monnard, Alex
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Through a simple 1,3-cycloaddition reaction, three BODIPY-peptide conjugates that target the extracellular domain of the epidermal growth factor receptor (EGFR) were prepared and their ability for binding to EGFR was investigated.
Tyrslai M. Williams +5 more
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