Results 11 to 20 of about 103,875 (262)

Effect of benzocyclobutadieno-annelation on cyclic conjugation in perylene

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2011
Earlier studies showed that the intensity of cyclic conjugation in the central ring R of perylene can be significantly altered by means of benzo-annelation. In particular, linear (resp. angular) benzoannelation was found to decrease (resp.
Ivan Gutman, Beba Stojanovska
doaj   +1 more source

Synthesis, structure, and properties of switchable cross-conjugated 1,4-diaryl-1,3-butadiynes based on 1,8-bis(dimethylamino)naphthalene

open access: yesBeilstein Journal of Organic Chemistry, 2023
A set of novel 1,4-diaryl-1,3-butadiynes terminated by two 7-(arylethynyl)-1,8-bis(dimethylamino)naphthalene fragments was prepared via the Glaser–Hay oxidative dimerization of 2-ethynyl-7-(arylethynyl)-1,8-bis(dimethylamino)naphthalenes.
Semyon V. Tsybulin   +4 more
doaj   +1 more source

Stability of bicalicene isomers: A topological study [PDF]

open access: yesJournal of the Serbian Chemical Society, 2016
Bicalicene is the conjugated hydrocarbon obtained by joining two calicene fragments. This can be done in two different ways, thus resulting in two bicalicene isomers (tentatively referred to as cis and trans).
Gutman Ivan
doaj   +1 more source

An Efficient Approach for the Design and Synthesis of Antimicrobial Peptide-Peptide Nucleic Acid Conjugates

open access: yesFrontiers in Chemistry, 2022
Peptide-Peptide Nucleic Acid (PNA) conjugates targeting essential bacterial genes have shown significant potential in developing novel antisense antimicrobials. The majority of efforts in this area are focused on identifying different PNA targets and the
Nitin A. Patil   +12 more
doaj   +1 more source

Topological properties of altan-benzenoid hydrocarbons [PDF]

open access: yesJournal of the Serbian Chemical Society, 2014
The main topological characteristics of altan-benzenoids are established. In particular, it is shown that the perimeter of Kekuléan altan-benzenoids is of size 4k , having a destablizing (antiaromatic) energy effect, similar to (4k)-annulenes.
Gutman Ivan
doaj   +1 more source

A simple mathematical model for the effect of benzoannelation on cyclic conjugation [PDF]

open access: yesJournal of the Serbian Chemical Society, 2011
In a series of earlier studies, it was established that benzoannelation in the angular (resp. linear) position relative to a ring R of a polycyclic conjugated π-electron system, increases (resp.
Gutman Ivan, Balaban Aexanru T.
doaj   +1 more source

Enantioselective Conjugate Allylation of Cyclic Enones [PDF]

open access: yesThe Journal of Organic Chemistry, 2011
Enantioselective organocatalytic 1,2-allylation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture of diastereomers. This appears to be a general method for the net enantioselective conjugate allylation of cyclic enones.
Douglass F, Taber   +2 more
openaire   +2 more sources

Phenyl-cyclopentadienyl rule

open access: yesMacedonian Journal of Chemistry and Chemical Engineering, 2012
Within a systematic study of cyclic conjugation in the benzo-annelated derivatives of acenaphthylene and fluoranthene, a general regularity was discovered, named phenyl-cyclopentadienyl rule (PCP rule).
Jelena Đurđević, Ivan Gutman
doaj   +1 more source

Expansivity and Roquette Groups [PDF]

open access: yes, 2014
One looks at expansive subgroups in particular examples of Roquette groups. This study is motivated by the importance of expansive subgroups in the theory of stabilizing bisets highlighted in [BouThe].
Monnard, Alex
core   +3 more sources

Click Conjugation of Boron Dipyrromethene (BODIPY) Fluorophores to EGFR-Targeting Linear and Cyclic Peptides

open access: yesMolecules, 2021
Through a simple 1,3-cycloaddition reaction, three BODIPY-peptide conjugates that target the extracellular domain of the epidermal growth factor receptor (EGFR) were prepared and their ability for binding to EGFR was investigated.
Tyrslai M. Williams   +5 more
doaj   +1 more source

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