Results 281 to 290 of about 635,495 (333)
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Exploring Synthetic Strategies for 1H-Indazoles and Their N-Oxides: Electrochemical Synthesis of 1H-Indazole N-Oxides and Their Divergent C-H Functionalizations.

Angewandte Chemie, 2023
The selective electrochemical synthesis of 1H-indazoles and their N-oxides and the subsequent C-H functionalization of the 1H-indazole N-oxides are described. The electrochemical outcomes were determined by the nature of the cathode material.
Sagar Arepally   +4 more
semanticscholar   +1 more source

Site-Specific Oxidative C-H Chalcogenation of (Hetero)Aryl-Fused Cyclic Amines Enabled by Nanocobalt Oxides.

Organic Letters, 2018
By employing reusable nanocobalt oxides as the catalysts, a site-specific oxidative C-H chalcogenation of (hetero)aryl-fused cyclic amines with various thiols and diselenides is presented for the first time. The reaction proceeds selectively at the sites
Zhenda Tan   +5 more
semanticscholar   +1 more source

Cyclization of N,N-diethylgeranylamine N-oxide in one-pot operation: preparation of cyclic terpenoid-aroma chemicals

Tetrahedron Letters, 2008
Acid promoted cyclization of the geranylamine N-oxide (E)-4 followed by base-catalyzed intramolecular aldol condensation afforded 1-acetyl-4,4-dimethyl-1-cyclohexene (7) in one-pot operation. Reduction of 7, which possess strong fruity odor, followed by lipase-catalyzed kinetic resolution furnished the acetate (R)-26 (>49.9% yield, >99% ee) and the ...
Kunihiko Takabe   +3 more
openaire   +1 more source

ChemInform Abstract: STRAINED CYCLIC ACETYLENES, VII. ADDITION OF SULFUR AND PYRIDINE N‐OXIDE TO SEVEN MEMBERED CYCLOALKYNES

Chemischer Informationsdienst, 1980
AbstractDie cyclischen Acetylene (Ia) und (Ib) addieren elementaren Schwefel zu den Dithieten (IIa) und (IIb), mit Pyridin‐N‐oxid (III) und (Ia) IÖO wird das Spiroazepin (IV) erhalten, das thermisch in das Pyridylthiepinon (V) umgelagert werden kann.
A. KREBS   +4 more
openaire   +1 more source

Bicyclic 1,2-oxazine N-oxides. Different behaviour in ring fission between systems derived from 5- and 6-membered ring cyclic enamines

Tetrahedron, 1982
Abstract 1,2-Oxazine N-oxides derived from aminocyclohexenes open into the corresponding nitroalkylated trisubstituted enamines, whereas those derived from aminocyclopentenes give stable tetrasubstituted enamines. Both open-chain systems are easily hydrolyzed to the corresponding γ-nitrocycloalkanones.
DANEO S.   +3 more
openaire   +2 more sources

ChemInform Abstract: Palladium‐Catalyzed Coupling Reactions of Thioimidate N‐Oxides: Access to α‐Alkenyl‐ and α‐Aryl‐Functionalized Cyclic Nitrones.

ChemInform, 2010
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Julie Schleiss   +2 more
openaire   +1 more source

A cyclic voltammetric study of some quinoxaline di-n-oxides and quinoxalines in acetonitrile: substituent effect on the cathodic reduction

Electrochimica Acta, 1987
Abstract The cathodic reductions of two series of substituted quinoxaline di- N -oxides and quinoxalines in acetonitrile were measured in the potential range of 0 to −2.0 V and 0 to −2.3 V vs sce , respectively. Two irreversible reductions were observed in the first series, and one reversible reduction for the second.
K.R. Barqawi, M.A. Atfah
openaire   +1 more source

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