Cyclic Voltammetry of Auranofin [PDF]
The oxidative behavior of Auranofin, 2,3,4,6‐tetra‐O‐acetyl‐1‐thio‐β ‐D‐glucopyranosato‐ S(triethylphosphine)gold(I), was investigated by using cyclic voltammetry (CV) in 0.1 M Bu4NPF6/CH2Cl2 and 0.1 M Bu4NPF4/CH2Cl2 solutions using Pt working and auxiliary electrodes and a Ag/AgCI reference.
Ahmed A. Mohamed+2 more
openaire +3 more sources
Cyclic voltammetry of polypyrroledodecylbenzenesulfonate layers [PDF]
Polypyrrole was deposited from solutions of NaClO4 and NaDBS, where DBS is dodecylbenzenesulfonate, in aqueous solution and characterized by voltammetry. It is found that the absence of the so‐called ‘double layer charging current’ during cyclic voltammetry of the layers formed from solutions with surfactant is not because of the order in morphology of
McCormac, T.+4 more
openaire +5 more sources
Detection of dairy fouling by cyclic voltammetry and square wave voltammetry [PDF]
AbstractFouling in food processing environment can cause the increase of production costs due to additional cleaning steps and risk of contamination of food products. There is a demand to introduce advanced techniques to detect fouling in food processing equipment.
Horst-Christian Langowski+6 more
openaire +5 more sources
First direct evidence of N-heterocyclic carbene in BMIm acetate ionic liquid. An electrochemical and chemical study on the role of temperature [PDF]
Cyclic voltammetry provides the first direct evidence of N-heterocyclic carbene (NHC) presence in neat 1-‐butyl-3-methylimidazolium acetate ionic liquid (BMImAcO) at 120°C. The NHC existence, proved by its oxidation current in cyclic voltammetry, was
Chiarotto, I., Feroci, M., Inesi, A.
core +1 more source
Electrophotocatalysis: Cyclic Voltammetry as an Analytical Tool [PDF]
Electrophotocatalysis (e-PC) is currently experiencing a renewed interest. By taking advantage of the highly oxidizing or reducing power of excited state of electrogenerated ion radicals, it allows thermodynamically difficult redox reactions to be performed. However, e-PC is facing various specific issues, such as its fundamentally heterogeneous nature,
Marie-Noëlle Collomb+3 more
openaire +5 more sources
On the use of electrochemical techniques to monitor free oxide content in molten fluoride media [PDF]
The electrochemical behaviour of oxide ions has been studied in fluoride melts(LiF/NaF eutectic) by cyclic voltammetry, square wave voltammetry and chronopotentiometry.
Barin+19 more
core +1 more source
Opportunities for mesoporous nanocrystalline SnO2 electrodes in kinetic and catalytic analyses of redox proteins [PDF]
PFV (protein film voltammetry) allows kinetic analysis of redox and coupled-chemical events. However, the voltammograms report on the electron transfer through a flow of electrical current such that simultaneous spectroscopy is required for chemical ...
Angove+16 more
core +1 more source
A combined "electrochemical-frustrated Lewis pair" approach to hydrogen activation: surface catalytic effects at platinum electrodes [PDF]
Herein, we extend our “combined electrochemical–frustrated Lewis pair” approach to include Pt electrode surfaces for the first time. We found that the voltammetric response of an electrochemical–frustrated Lewis pair (FLP) system involving the B(C6F5)3 ...
Ashley+48 more
core +2 more sources
Electrochemical study of the Eu(III)/Eu(II) system in molten fluoride media [PDF]
The electrochemical behaviour of the Eu(III)/Eu(II) system was examined in the molten eutectic LiF-CaF2 on a molybdenum electrode, using cyclic voltammetry, square-wave voltammetry and chronopotentiometry. It was observed that EuF3 is partly reduced into
Cassayre, Laurent+3 more
core +1 more source
Electropolymerization of phenol on a vitreous carbon electrode in acidic aqueous solution at different temperatures [PDF]
Electrochemical oxidation of phenol in acidic aqueous solution was studied on a vitreous carbon electrode at different temperatures in the range of 25–85 °C by cyclic voltammetry and chronoamperometry.
Belhadj Tahar, Noureddine+1 more
core +1 more source