Results 51 to 60 of about 92,312 (258)

Electrochemical Reduction of [Ni(Mebpy)3]2+. Elucidation of the Redox Mechanism by Cyclic Voltammetry and Steady-State Voltammetry in Low Ionic Strength Solutions.

open access: yes, 2020
Bipyridine complexes of Ni are used as catalysts in a variety of reductive transformations. Here, the electroreduction of [Ni(Mebpy)3]2+ (Mebpy = 4,4’-dimethyl-2,2’-bipyridine) in dimethylformamide is reported, with the aim of determining the redox ...
Yinghua, Qiu   +7 more
core   +1 more source

Dipole‐Engineered Conductive Additives for Ultrastable Interphase Evolution in High‐Areal‐Capacity Silicon Anodes

open access: yesAdvanced Functional Materials, EarlyView.
In the work reported herein, dipole‐engineered sulfonated carbon nanofibers enable conductive additives to actively regulate interphase formation in silicon anodes. Polar sulfonyl groups guide electrolyte decomposition to form a compact LiF‐rich interphase while promoting robust integration with silicon.
Song Kyu Kang   +6 more
wiley   +1 more source

Tuning Separator Chemistry: Improving Zn Anode Compatibility via Functionalized Chitin Nanofibers

open access: yesAdvanced Functional Materials, EarlyView.
Nanochitin derived from waste shrimp shells is used to fabricate separators for aqueous zinc batteries. By tuning the density of amine and carboxylic surface groups, water mobility at the separator interface is controlled, promoting uniform zinc deposition, suppressing dendrite growth, and enabling exceptional cycling stability exceeding 2000 h ...
Ibrahim Al Kathemi   +6 more
wiley   +1 more source

Fast-Scan Cyclic Voltammetry - Scanning Electrochemical Microscopy

open access: yes, 2007
The use of fast scan cyclic voltammetry (FSCV) to generate images in scanning electrochemical microscopy is demonstrated. In the FSCV-SECM method a cyclic voltammogram is acquired at each grid point of the scanned area. Thus, each point in the SECM image
Díaz-Ballote, Luis   +2 more
core   +1 more source

Interplay Between Phase Evolution, Fe Migration, and Oxygen Redox in O3‐Type NaxFeyMn1−yO2 Cathodes

open access: yesAdvanced Functional Materials, EarlyView.
Why do Na‐ion battery cathodes, that are compositionally closely related, follow different structural paths during battery operation? This work shows how Fe content controls when iron atoms migrate from their original sites. Early migration locks the layers and blocks key phase transitions, whereas delayed migration permits fuller structural ...
Morten Johansen   +4 more
wiley   +1 more source

Fast Cyclic Voltammetry of Self-assembled Alkanethiol and Hybridized DNA on Gold Plates for Novel Field Effect Transistor Sensors

open access: yes, 2008
Fast Cyclic Voltammetry of Self-assembled Alkanethiol and Hybridized DNA on Gold Plates for Novel Field Effect Transistor ...
徐芬, 孙立贤, 曹忠
core  

Cyclic voltammetry of polypyrroledodecylbenzenesulfonate layers

open access: yes, 1994
Polypyrrole was deposited from solutions of NaCIO. and NaDBS, where DBS is dodecylbenzenesulfonate in aqueous soluion and characterizcd by voltammetry.
Cassidy, John F   +5 more
core   +1 more source

Long‐Range Coordination Environment Modulates Single‐Atom Local States and Systemic Impact on CO2 Photoconversion

open access: yesAdvanced Functional Materials, EarlyView.
Terminal groups on Cu porphyrins modulate the electronic states of single‐atom Cu centers through a long‐range electronic effect, without altering the Cu coordination geometry. Meanwhile, a multi‐descriptor framework is established that incorporates porphyrin regulation, hybrid catalyst properties, and CO2 photoreduction capabilities.
Yi Zhang   +13 more
wiley   +1 more source

Tailoring Li‐ion Storage and Transport in Two‐Dimensional Conjugated Metal‐Organic Frameworks via Precise Nitrogen Incorporation

open access: yesAdvanced Functional Materials, EarlyView.
Two nitrogen‐doped 2D conjugated metal‐organic frameworks (2D c‐MOFs, namely Cu‐Nx‐OHBA, x = 2 or 4) are synthesized, featuring precise nitrogen incorporation via rational ligand design. The Cu‐Nx‐OHBA 2D c‐MOFs are largely tailorable by varying skeletal nitrogen density, with respect to electrical conductivity, Li‐storage capacitance, and Li‐transport
Xiangyu Li   +7 more
wiley   +1 more source

Influence of electrode roughness on cyclic voltammetry

open access: yes, 2008
Electrodes with rough surfaces are of great practical importance from both applied and fundamental points of view. The diffusion domain approach is used to model cyclic voltammetry at such electrodes.
Compton, RG   +3 more
core   +1 more source

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