Results 221 to 230 of about 72,904 (250)

2,3‐Dichloro‐5,6‐Dicyano‐1,4‐Benzoquinone (DDQ)‐Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems

open access: yesChemistryOpen, EarlyView.
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley   +1 more source

Diverse reactivity of maleimides in polymer science and beyond

open access: yesPolymer International, Volume 74, Issue 4, Page 296-306, April 2025.
This mini‐review provides a thorough overview of maleimide chemistry, highlighting its diverse reactivity in polymer and materials science applications. Abstract Maleimides are remarkably versatile functional groups, capable of participating in homo‐ and copolymerizations, Diels–Alder and (photo)cycloadditions, Michael additions, and other reactions ...
Bruce E Kirkpatrick   +2 more
wiley   +1 more source

Advances in conjugated porous polymers via high internal phase emulsion templating

open access: yesPolymer International, EarlyView.
This mini‐review highlights the design, synthesis and potential applications of π‐conjugated polyHIPEs, emphasizing their unique hierarchical structure and tunable properties. The work outlines innovative synthetic strategies and explores their promising roles in photocatalysis and environmental remediation, paving the way for future advancements in ...
Julie‐Lisa Malaval   +4 more
wiley   +1 more source

Impact of polymer aging on main‐chain poly(fullerene)s with halide chain‐ends for inverted perovskite solar cells

open access: yesPolymer International, EarlyView.
Subtle variations in halogen chemistry significantly affect the aging behavior of polymeric electron transport layers in inverted perovskite solar cells, underscoring the importance of precise chemical design for enhancing long‐term stability. Abstract As perovskite solar cells (PSCs) advance toward commercialization, the need for stable and easily ...
João V. Paulin   +7 more
wiley   +1 more source

Structure and Mechanism of PhdC, a Prenylated‐Flavin Maturase

open access: yesProteins: Structure, Function, and Bioinformatics, EarlyView.
ABSTRACT Prenylated flavin mononucleotide (prFMN) is a modified flavin cofactor required by the UbiD family of (de)carboxylase enzymes. While the reduced prFMNH2 form is produced by the flavin prenyltransferase UbiX, the corresponding two‐electron oxidized prFMNiminium form is required to support UbiD catalysis. Thus, oxidative maturation of prFMNH2 is
Dominic R. Whittall   +4 more
wiley   +1 more source
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Cycloaddition Reactions

2010
This chapter deals with enantioselective organocatalytic cycloaddition reactions. Several cinchona alkaloids have been recently demonstrated as efficient chiral organocatalysts for enantioselective Diels−Alder reactions. Thus, excellent results were obtained for the Diels−Alder reaction of 3-vinylindoles with maleimides catalysed by a ...
S. Araki, T. Hirashita
  +4 more sources

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