Results 31 to 40 of about 108,727,180 (62)

Crystal Structure, DFT Calculation, and Hirshfeld Surface Analysis of the 1-(Cyclohex-1-en-1-yl)-3-(prop-2-yn-1-yl)-1,3-dihydro-2H-benzimidazol-2-one

, 2023
In this paper, we describe the synthesis and structural characterization of the 1-(cyclohex-1-en-1-yl)-3-(prop-2-yn-1-yl)-1,3-dihydro-2H-benzimidazol-2-one (2) via IR, NMR (1H and 13C), and HRMS.
Baouid, Abdesselam, Ismail Hdoufane, Abdesselam Baouid, Loughzail, Mohamed, Fleutot, Solenne, Mohamed Loughzail, Marouane Ait Lahcen, Henia Bouzidi Mousser, Michel François, Adardour, Mohamed, François, Michel, Cherqaoui, Driss, Hdoufane, Ismail, Driss Cherqaoui, Mousser, Hénia, Ait Lahcen, Marouane, Mohammed Alanazi, Solenne Fleutot, Alanazi, Mohammed, M, Mohammed M. Alanazi, Mohamed Adardour   +20 more
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Synthesis of primary alcohol 4.

, 2018
Reagents and conditions: (a) 4-aminopyrazole hydrochloride, Et3N, DMF, 87%; (b) cyclohex-1-en-1-ylboronic acid, 2-(cyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, PdCl2dppf, K3PO4, dioxane/water, 90°C, 46%; (c) ethyl 2-bromoacetate, K2CO3 ...
Kevin Cusack (5728823), Dawn M. George (1692688), Jeremy J. Edmunds (1692718), Jacqueline Loud (5728829), David B. Duignan (1692706), Michael Hoemann (5728826), Terry Melim (5330360), Regina Mario (5544320), Kelly Mullen (5728832), Gagandeep Somal (5728835), Raymond J. Huntley (2524474), Lu Wang (45927)   +11 more
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Syntheses of 2,3-dihydroxycyclohexylacetic acid γ-lactones

, 1972
Oxidation of cyclohex-2-enylacetic acid with performic acid gives 2-cis-3-trans dihydroxycyclohexylacetic acid γ-lactone. Oxidation with neutral aqueous permanganate solution gives two diols, 2-cis-3-cis-dihydroxycyclohexylacetic acid and 2-trans-3-trans-
Browne, Alan Robert
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Metabolism of Benzoate, Cyclohex-1-ene Carboxylate, and Cyclohexane Carboxylate by “ Syntrophus aciditrophicus ” Strain SB in Syntrophic Association with H ₂ -Using Microorganisms

, 2001
The metabolism of benzoate, cyclohex-1-ene carboxylate, and cyclohexane carboxylate by “ Syntrophus aciditrophicus ” in cocultures with hydrogen-using microorganisms was studied. Cyclohexane carboxylate, cyclohex-1-ene carboxylate,
Mostafa S. Elshahed, Vishvesh K. Bhupathiraju, Neil Q. Wofford, Mark A. Nanny, Michael J. McInerney   +4 more
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Synthesis of carboxylic acid 6.

, 2018
Reagents and conditions: (a) TsCl, pyridine, 0°C to rt, 80%; (b) 4-nitropyrazole, Cs2CO3, DMF, 77%; (c) 10% Pd/C, H2 (1 atm), THF/EtOH, rt, 93%; (d) 24, Et3N, DMF, rt, 97%; (e) cyclohex-1-en-1-ylboronic acid, Pd(PPh3)2Cl2, Cs2CO3, 1,4-dioxane/water, 90°C,
Kevin Cusack (5728823), Dawn M. George (1692688), Jeremy J. Edmunds (1692718), Jacqueline Loud (5728829), David B. Duignan (1692706), Michael Hoemann (5728826), Terry Melim (5330360), Regina Mario (5544320), Kelly Mullen (5728832), Gagandeep Somal (5728835), Raymond J. Huntley (2524474), Lu Wang (45927)   +11 more
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Organocatalytic Asymmetric Synthesis of 5-(Trialkylsilyl)cyclohex-2-enones and the Transformation into Useful Building Blocks

, 2016
A simple organocatalytic approach to highly attractive chiral building blocks is presented. By the reaction of β-ketoesters with α,β-unsaturated aldehydes using a chiral TMS-protected prolinol as the catalyst, optically active 5-(trialkylsilyl)cyclohex-2-
Karl Anker Jørgensen (1287900), Patrick Bolze (2421316), Gustav Dickmeiss (2115661)   +2 more
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The 9-Decalyl and Related cations VII. Solvolysis of 3-(Cyclohex-1′-enyloxy)propyl p-Nitrobenzenesulfonate

, 1985
The solvolysis of 3-(cyclohex-1′-enyloxy) propyl p- nitrobenzenesulfonate (5) in ethanol buffered separately with sodium ethoxide and triethylamine and 2,2,2-trifluoroethanol buffered with triethylamine has been investigated. Kinetic determinations
PH Ferber, TI Stoneman, GE Gream
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High Pressure Elicits Unexpected Transformations of Plain Nitroaromatics with 4-(Cyclohex-1-en-1-yl)morpholine

, 2018
International audienceReacting simple nitroarenes with the readily available enamine 4‐(cyclohex‐1‐en‐1‐yl)morpholine leads to unexpected reaction sequences under high pressure.
Morgane Sanselme, Michael De Paolis, Diab, Sonia, Noël-Duchesneau, Ludovik, Chataigner, Isabelle, Kondo, Yoshinori, Sonia Diab, Isabelle Chataigner, de Paolis, Michaël, Ludovik Noël-Duchesneau, Sanselme, Morgane, Yoshinori Kondo   +11 more
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Synthesis of secondary alcohol 1.

, 2018
Reagents and conditions: (a) 4-nitropyrazole, Cs2CO3, DMF, 77% (b) PPTS, acetone/H2O, 88%; (c) NaBH4, EtOH, -5°C; recrystallization from toluene, 59%; (d) Pd/C, H2 (1 atm), MeOH, rt, 98%; (e) 24, DIPEA, DMF, rt, 97%; (f) cyclohex-1-en-1-ylboronic acid ...
Kevin Cusack (5728823), Dawn M. George (1692688), Jeremy J. Edmunds (1692718), Jacqueline Loud (5728829), David B. Duignan (1692706), Michael Hoemann (5728826), Terry Melim (5330360), Regina Mario (5544320), Kelly Mullen (5728832), Gagandeep Somal (5728835), Raymond J. Huntley (2524474), Lu Wang (45927)   +11 more
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Formation of a Ruthenium(II) Dicyclohexyl(η²-cyclohex-3-enyl)phosphine Hydride Complex from an Alkylidene Precursor

, 2016
Treatment of Ru(CHPh)Cl2(PCy3)2 (Cy = cyclohexyl) with K[N(i-Pr2PS)2] afforded a mixture of Ru(CHPh)[N(i-Pr2PS)2](PCy3)Cl (1) and Ru(CHPh)[N(i-Pr2PS)2]2 (2).
Wai-Hang Chiu (1985746), Ian D. Williams (1642513), Wai-Man Cheung (1753819), Qian-Feng Zhang (1753822), Xiao-Yi Yi (1911823), Wa-Hung Leung (1753816)   +5 more
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