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A deoxyfluoroalkylation-aromatization strategy to access fluoroalkyl arenes.
Chem Commun (Camb)Bhattarai P, Koley S, Goel K, Altman RA.
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Toxicological aspects of cyclohexanone
Toxicology and Applied Pharmacology, 1979Abstract A toxicity evaluation of cyclohexanone was conducted using oral, intraperitoneal, dermal, intradermal, ophthalmic, and/or inhalation exposure to various species of animals. Cyclohexanone induced diverse reactions by virtue of a general vascular or tissue reaction and CNS depression. The ip LD50 for mice, rats, guinea pigs, and rabbits ranged
P K, Gupta +3 more
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Oxovanadium(IV) complexes of cyclohexanone semicarbazone and cyclohexanone thiosemicarbazone
Transition Metal Chemistry, 1981Oxovanadium(IV) complexes, VOL2X2 (X = Cl, Br and 0.5 SO4), have been synthesised and characterised by elemental analysis, room temperature magnetic moment, electronic, i.r. and electron spin resonance studies. The complexes are hexacoordinate and have a distorted octahedral structure.
Sulekh Chandra, Krishna B. Pandeya
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Some chromium(III) complexes of cyclohexanone semicarbazone and cyclohexanone thiosemicarbazone
Journal of Inorganic and Nuclear Chemistry, 1980Chromium(III) complexes of cyclohexanone semicarbazone and cyclohexanone thiosemicarbazone have been prepared and characterized. Complexes of general composition Cr(ligand)2X3 are obtained (X = Cl or NO3). Magnetic moments, electronic spectra and ESR spectra of the complexes are discussed.
Sulekh Chandra, K.B. Pandeya, R.P. Singh
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Canadian Journal of Research, 1931
In the presence of a small amount of sodium methylate, cyclohexanone and benzil form an addition product, which is a "semicyclic" 1:4-diketone. No derivatives of a bicyclic cyclo-heptane were found. Its most conspicuous chemical property is its sensitivity to mineral acids; among the reaction products is found a diphenyltetrahydrocumarone.
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In the presence of a small amount of sodium methylate, cyclohexanone and benzil form an addition product, which is a "semicyclic" 1:4-diketone. No derivatives of a bicyclic cyclo-heptane were found. Its most conspicuous chemical property is its sensitivity to mineral acids; among the reaction products is found a diphenyltetrahydrocumarone.
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Mechanistic studies on cyclohexanone oxygenase
Biochemistry, 1982The bacterial flavoprotein monooxygenase carries out an oxygen insertion reaction on cyclohexanone, with ring expansion to form the seven-membered cyclic product epsilon-caprolactone, a transformation quite distinct from the phenol leads to catechol transformation carried out by the bacterial flavoprotein aromatic hydroxylases.
C C, Ryerson, D P, Ballou, C, Walsh
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