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Photoredox radical/polar crossover enables C-H gem-difunctionalization of 1,3-benzodioxoles for the synthesis of monofluorocyclohexenes. [PDF]

Chem Sci, 2023
Tian J, Zhou L.
europepmc +1 more source

Metabolism of Drugs. XXV. Biotransformation of Drugs having Cyclohexene Ring. (2). Metabolic Fate of 2-Substituted Cyclohexenylglutarimides.

, 1961
Hisao Tsukamoto, Minoru Yoshimura
openalex +2 more sources

Regio‐, Stereoselective, Aerobic and Metal‐Free Synthesis of Z‐Vinyl Sulfides: One‐Pot Hydroiodination of Internal Alkynes and in situ Sulfenylations

Advanced Synthesis &Catalysis, Volume 367, Issue 13, July 23, 2025.
Abstract A novel, metal‐free, air‐ and moisture‐compatible one‐pot tandem protocol for the regio‐ and stereoselective synthesis of Z‐vinyl sulfides (achieving yields up to 99%), is reported. This straightforward and efficient process combines the selective hydroiodination of internal alkynes, promoted by the eutectic mixture choline iodide (ChI)/p‐TsOH
Gloria Morís‐Menéndez +5 more
wiley +1 more source

Electrochemical Oxidative Radical Polar Crossover Route to 1,4‐Keto Carboxylates Mediated by Anchimeric Assistance

Chemistry – A European Journal, Volume 31, Issue 41, July 22, 2025.
In this work we developed an electrochemical method for 1,4‐dioxygenated compounds, offering broad scope, functional group compatibility, and diastereoselectivity. Abstract The 1,4‐keto carboxylate scaffold is present in the structure of many biologically relevant compounds.
Ian MacLean +5 more
wiley +1 more source

Catalytic Epoxidation of Cyclohexene witht-Butyl Hydroperoxide in the Presence of Various Molybdenum Complexes [PDF]