Notizen: Photoreaktion zwischen α-Chlor-i-butyraldehyd und Cyclohexen / The Photolytic Reaction of α-Chloroisobutyraldehyde with Cyclohexene [PDF]
Hans‐Ingo Joschek
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Mass spectrometry in structural and stereochemical problems. Part 178 - The electron-impact promoted fragmentation of 1,2-cyclohexene oxide [PDF]
Mass spectra of 1,2-cyclohexane oxide and three deuterium labeled ...
Brown, P., Djerassi, C., Strong, M. K.
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Sacrificial Biofabrication for Vascularization: Concept, Materials, Technologies, and Applications
Vasculature is indispensable for tissue viability in regenerative medicine. The sacrificial biofabrication enables precise fabrication of vascular channels by using temporary templates that are subsequently removed. This review defines the concept and delves into sacrificial materials, surrounding materials, fabrication technologies, and biomedical ...
Jiezhong Shi +7 more
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Synthesis and Properties of the Stereoisomeric Triethyl 2-Aminocyclohexane-1,5,5-tricarboxylates [PDF]
Hydrogenation of triethyl 2-oxyiminocyclohexane-1,5,5-tricarboxylate (I) over Raney nickel in isopr-0panol afforded the two stereoisomeric triethyl 2-aminocyclohexane-1,5,5-tricarboxylates (II).
B. Djuras, V. Škarić, Đ. Škarić
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Fun with radicals: Some new perspectives for organic synthesis
International audienceThe degenerative radical addition-transfer of xanthates onto alkenes allows the rapid assembly of richly functionalized structures.
Quiclet-Sire, Béatrice, Zard, Samir,
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A rhodium(II)‐catalyzed ring expansion of stereodefined dihydro‐1,3‐thiazines with diazomalonates gives 1,4‐thiazepines via a sulfonium ylide rearrangement. The reaction shows a cis/trans reactivity divergence arising from different metal coordination, as revealed by experiments and density functional theory studies.
Laurine Tual +3 more
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Cis- and Trans-Chlorination of Cyclohexene by Antimony Pentachloride and Triethyloxonium Hexachloroantimonate [PDF]
Fuminori Akiyama +2 more
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Citrus reticulata Blanco: A Review on Chemical Composition and Biological Activities
This review compiles chemical information and biological activities from 49 studies on Citrus reticulata. The fruit peels stand out for their high content of methoxylated monoterpenes and flavonoids with antioxidant, anti‐inflammatory, and antimicrobial activities.
José Walber Gonçalves Castro +3 more
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Cycloaddition of CO2 to Epoxides Using Bifunctional Triphenylphosphonium Catalysts
Metal‐free phosphonium‐pyridine catalysts enable the solvent‐free fixation of carbon dioxide with diverse epoxides at 1 amt, including challenging bio‐based terpenes. ABSTRACT A series of pyridine‐grafted triphenylphosphonium salts [Ph3P+R]Cl− (R = benzyl (1), pyridine‐2‐ylmethyl (2), pyridine‐3‐ylmethyl (3), and pyridine‐4‐ylmethyl (4)) were ...
Afshin Enferadikerenkan +6 more
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