Results 81 to 90 of about 7,352 (256)

Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents

open access: yesPolymer International, EarlyView.
The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler   +4 more
wiley   +1 more source

Trigonal Planar Bis(carbene)Cu(I) Complexes Enable Divergent H2 Activation with H2O for Accelerated Olefin Hydrogenation

open access: yesAngewandte Chemie, Volume 137, Issue 33, August 11, 2025.
Trigonal planar naphthyridine‐bis(carbene)Cu(I) alkyl, hydroxide, and ethoxide complexes promote a divergent mechanism of H2 activation for the rare catalytic hydrogenation of unactivated alkenes at mild conditions at copper. Abstract CuH‐catalyzed olefin hydrogenation is rare compared to those of carbonyl‐derived substrates. Olefin insertion into Cu–H
Evan A. Patrick   +6 more
wiley   +2 more sources

A metal-free carbon catalyst for oxidative dehydrogenation of aryl cyclohexenes to produce biaryl compounds. [PDF]

open access: yesProc Natl Acad Sci U S A, 2023
Yang M   +8 more
europepmc   +1 more source

Schiff based derived homogeneous catalysts for ring‐opening terpolymerization

open access: yesPolymer International, EarlyView.
One‐pot synthesis of degradable terpolymers from l‐lactide, propylene oxide and CO₂ using diverse catalysts is described, revealing structure–property relationships for tailored applications in sustainable materials. Abstract In this study, we synthesized and evaluated a series of Schiff base cobalt catalysts for the terpolymerization of propylene ...
Akanksha Ranade, Amjad Ali, Rajeev Mehta
wiley   +1 more source

Recent progress of heterocycle ring‐opening (co)polymerization for the synthesis of sequence‐controlled block polyesters and polycarbonates

open access: yesSmart Molecules, EarlyView.
Block copolymers are fundamental for the development of smart molecules. Aliphatic polyesters and polycarbonates have received attention as heteroatom‐containing polymers that are biodegradable and biocompatible. Block polymers from polyesters and polycarbonates have the ability to form smart molecules. This review presents the heterocycle monomer ring‐
Hongyu Zhao   +3 more
wiley   +1 more source

LIQUID-PHASE OXIDATION OF CYCLOHEXENE IN THE PRESENCE OF BENZALDEHYDE [PDF]

open access: bronze, 1966
Tsuneo Ikawa   +3 more
openalex   +1 more source

Woodward and Hoffmann on Secondary Orbital Interactions. How to Make a Fine Two‐Course Meal from Leftovers**

open access: yesThe Chemical Record, EarlyView.
In February through April 1965, Hoffmann devised several MO tools to explain the regiochemistry of the Diels‐Alder and the preference of the Cope reaction to proceed by the chair rather than boat orientations, when both were possible. The secret lay in secondary orbital interactions that were revealed through qualitative perturbation theory.
Jeffrey I. Seeman
wiley   +1 more source

Polyoxygenated cyclohexene derivatives and other constituents of Uvaria rufa stem. [PDF]

open access: yesPhytochemistry, 2023
Gurgul A   +7 more
europepmc   +1 more source

Home - About - Disclaimer - Privacy