Enantioselective dearomative formal (3+3) cycloadditions of bicyclobutanes with aromatic azomethine imines: access to fused 2,3-diazabicyclo[3.1.1]heptanes. [PDF]
Yang XC, Wu F, Wu WB, Zhang X, Feng JJ.
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Organocatalytic Asymmetric Synthesis of Azabicyclo[2.1.1]hexanes. [PDF]
Alama L+4 more
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Silver-catalyzed direct conversion of epoxides into cyclopropanes using N-triftosylhydrazones. [PDF]
Li L+9 more
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Recent advances in catalytic asymmetric alkenyl C(sp<sup>2</sup>)-H bond functionalizations. [PDF]
Si XJ, Wang TC, Loh TP, Lu MZ.
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High-Valent Copper Catalysis Enables Regioselective Fluoroarylation of Gem-Difluorinated Cyclopropanes. [PDF]
Wu X, Song X, Xia Y.
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Transition-metal-free regioselective synthesis of spiro-oxazolidines through [3 + 2] annulation reactions of azadienes with haloalcohols. [PDF]
Savekar AT+3 more
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Terminal Cyclopropylsilyl Alcohols as Useful Key Units to Access 2,3,4,6-Tetrasubstituted Tetrahydropyran Scaffolds by Stereocontrolled Prins Cyclization. [PDF]
Peña LF, Barbero A.
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A new ionic cyclopropanation process involving the addition of diazo esters to donor-acceptor cyclopropanes (DAC) activated by GaCl3 has been developed. The reactions occur via 1,2-zwitterionic gallium complexes with elimination of nitrogen in all cases to give 1,1,2,3-tetrasubstituted cyclopropanes as the main products.
Irina A. Borisova+5 more
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The cyclopropanated derivatives of three diesel-compatible biofuels—limonene, turpentine, and canola oil methyl ester—were prepared. Their heats of combustion were both calculated using theoretical methods and measured experimentally, and it was found that for all three compounds the specific energy (in kJ/g) was similar to that of the starting ...
Olivier Lebel, Alexandre Langlois
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