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Cationic and Anionic Disorder in CZTSSe Kesterite Compounds: A Chemical Crystallography Study
Inorganic Chemistry, 2017The cationic and anionic disorder in the Cu2ZnSnSe4-Cu2ZnSnS4 (CZTSe-CZTS) system has been investigated through a chemical crystallography approach including X-ray diffraction (in conventional and resonant setup), 119Sn and 77Se NMR spectroscopy, and high-resolution transmission electron microscopy (HRTEM) techniques.
Pierre Bais +6 more
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Suppressing Element Inhomogeneity Enables 14.9% Efficiency CZTSSe Solar Cells
Advanced MaterialsAbstractKesterites, Cu2ZnSn(SxSe1−x)4 (CZTSSe), solar cells suffer from severe open‐circuit voltage (VOC) loss due to the numerous secondary phases and defects. The prevailing notion attributes this issue to Sn‐loss during the selenization. However, this work unveils that, instead of Sn‐loss, elemental inhomogeneity caused by Cu‐directional diffusion ...
Changcheng Cui +2 more
exaly +3 more sources
Inkjet-printed CZTSSe absorbers and influence of sodium on device performance
Solar Energy Materials and Solar Cells, 2018Abstract Inkjet printing is a promising route for thin film deposition due to its low material wastage and potential of high throughput production. In this work, the inkjet printing technique is used for the deposition of Cu2ZnSn(SxSe1−x)4 (CZTSSe) thin films from Cu-Zn-Sn-S molecular inks.
Xianzhong Lin +7 more
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Promoting effect of lanthanum doping on photovoltaic performance of CZTSSe solar cells
The Journal of Chemical PhysicsA large open-circuit voltage (VOC) deficit is the major challenge hindering the efficiency improvement of Cu2ZnSn(S,Se)4 (CZTSSe) solar cells. Cation substitution, or doping, is usually an effective strategy to achieve carrier regulation and improve efficiency.
Zhengjun Luo +8 more
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The Multiple Roles of Na Ions in Highly Efficient CZTSSe Solar Cells
SmallAbstract Sodium (Na) doping is a well‐established technique employed in chalcopyrite and kesterite solar cells. While various improvements can be achieved in crystalline quality, electrical properties, or defect passivation of the absorber materials by incorporating Na, a comprehensive demonstration of the desired
Wentong Yang +11 more
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Crystallization Behavior of CZTSSe by Selenization of Sputtered CZTS Precursors
2014In this work, we study the effect of annealing on crystallization behavior of Cu2ZnSn(SxSe1-x)4 (CZTSSe) absorbers. Cu-Zn-Sn-S precursors are deposited on glass/Mo substrate by cosputtering of Cu, ZnS, and SnS. In order to have a better understanding of the mechanisms of formation of CZTSSe and secondary phases during annealing, the effect of annealing
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Defect suppression for high-efficiency kesterite CZTSSe solar cells: Advances and prospects
Chemical Engineering Journal, 2023Changcheng Cui +2 more
exaly
Enhancing carrier transport in flexible CZTSSe solar cells via doping Li strategy
Journal of Energy Chemistry, 2022Qiong Yan, Quanzhen Sun, Hui Deng
exaly

