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Enhancing CZTSSe solar cells through electric field induced ion migration

Journal of Materials Chemistry A, 2022
Solar cells made from Cu2ZnSn(S,Se)4 (CZTS)-derived materials have been widely studied for their favourable material properties utilized in photovoltaic energy conversion.
A. O'Neill   +6 more
openaire   +1 more source

Modeling of CZTSSe solar photovoltaic cell for window layer optimization

Optik, 2020
Abstract Large and long-term future development of solar cells requires abundant non-toxic material like silicon. CZTSSe has emerged as next-generation solar material with an excellent candidate having better performance than previously studied compounds.
null Sadanand, DK Dwivedi
openaire   +1 more source

Fabrication of 7.2% Efficient CZTSSe Solar Cells Using CZTS Nanocrystals

Journal of the American Chemical Society, 2010
Earth abundant copper-zinc-tin-chalcogenide (CZTSSe) is an important class of material for the development of low cost and sustainable thin film solar cells. The fabrication of CZTSSe solar cells by selenization of CZTS nanocrystals is presented. By tuning the composition of the CZTS nanocrystals and developing a robust film coating method, a total ...
Qijie, Guo   +6 more
openaire   +2 more sources

The effect of Rb doping on CZTSSe solar cells

Solar Energy, 2019
Abstract Alkali metal doping is a promising method to enhance the performance of Cu2ZnSn(Se,S)4 (CZTSSe) solar cells due to its excellent effect on Cu(In,Ga)Se2 (CIGS) solar cells. In this work, rubidium (Rb) was doped in CZTSSe absorbers by sputtering Rb doped Cu2ZnSnS4 (CZTS) target with subsequent H2Se contained annealing.
Yixuan Wu   +12 more
openaire   +1 more source

Suppressing Element Inhomogeneity Enables 14.9% Efficiency CZTSSe Solar Cells

Advanced Materials
AbstractKesterites, Cu2ZnSn(SxSe1−x)4 (CZTSSe), solar cells suffer from severe open‐circuit voltage (VOC) loss due to the numerous secondary phases and defects. The prevailing notion attributes this issue to Sn‐loss during the selenization. However, this work unveils that, instead of Sn‐loss, elemental inhomogeneity caused by Cu‐directional diffusion ...
Yimeng Li   +8 more
openaire   +2 more sources

Trap density simulations on CZTSSe solar cells with AMPS-1D

Journal of Materials Science: Materials in Electronics, 2018
This work involves the simulation of Cu2ZnSn(S,Se) (CZTSSe) solar cell in analysis of microelectronic and photonic structures (AMPS-1D) while taking into account previous experimental and theoretical data on CZTS, CZTSe, CZTSSe, CdS and ZnO based devices. We start from the results of the champion CZTSSe solar cell with an efficiency of 12.6%.
J. Conde   +5 more
openaire   +1 more source

Enhancing the performance of CZTSSe solar cells with Ge alloying

Solar Energy Materials and Solar Cells, 2012
Abstract The ability to alloy Cu2ZnSn(S,Se)4 with Ge provides a unique ability to band-gap engineer the absorber film by controlling the relative cation ratios. In here, a preliminary study on adjusting the Ge to Sn ratio is shown to significantly improve the device performance of CZTSSe thin film solar cells.
Qijie Guo   +5 more
openaire   +1 more source

Optical and electrical modeling of CZTSSe based thin-film solar cells

Physica Scripta, 2023
Abstract This research utilized an optical and electrical model to examine the impact of optical and recombination losses on the short circuit current density , J sc , and conversion efficiency of thin-film ...
H A Mohamed   +3 more
openaire   +1 more source

Earth-Abundant Cu2ZnSn(S,Se)4 (CZTSSe) Solar Cells

2015
In recent years, copper (Cu)-based quaternary kesterite compounds—Cu2ZnSnS4 (CZTS), Cu2ZnSnSe4(CZTSe), and mixed chalcogenide Cu2ZnSn(SxSe1−x)4 (CZTSSe) have emerged as the potential alternative to the existing CIGS and CdTe absorbers in thin film solar cells.
Sandip Das   +2 more
openaire   +1 more source

8.6% Efficient CZTSSe Solar Cells Sprayed from Water–Ethanol CZTS Colloidal Solutions

The Journal of Physical Chemistry Letters, 2014
Copper zinc tin sulfide-selenide, Cu2ZnSn(S1-xSex)4 (CZTSSe), thin film photovoltaic devices were fabricated using a fast and environmentally friendly preparation method, consisting of the following steps: An instantaneous synthesis of a Cu-Zn-Sn-S (no Se) colloid, a nonpyrolytic spray of a dispersion of this colloid in a water-ethanol mixture, and a ...
Gerardo, Larramona   +9 more
openaire   +2 more sources

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