Results 61 to 70 of about 648 (164)

ESR Studies of Chemically Dehydrofluorinated Poly(vinylidene fluoride)

open access: yesMagnetic Resonance in Solids. Electronic Journal, 2008
X-band ESR of chemically dehydrofluorinated poly(vinylidene fluoride) films has been studied in the 150 ÷ 375 K temperature range. Dehydrofluorinated films reveal an ESR signal with g-factor close to that of the free electron. The ESR parameters (integral intensity, width, g-factor) of the samples depend on duration of the chemical reaction, storage ...
Mavrinskaya, N.   +5 more
openaire   +2 more sources

Electrochemical Partial Fluorination of Organic Compounds. 74. Efficient Anodic Synthesis of 2-Fluoro- and 2,3-Difluoro-2,3-dihydrobenzofuran Derivatives1

open access: yes, 2016
Anodic fluorination of 3-substituted benzofuran derivatives in a variety of fluoride salts resulted in the formation of three fluorinated products; two stereoisomers of 2,3-difluoro-2,3-dihydrobenzofuran (cis and trans) and cis-2-fluoro-3-hydroxy-2,3 ...
Toshio Fuchigami (2073130)   +1 more
core   +1 more source

Selective Defluorination Approach to N-Cbz-3,3-difluoro-2-difluoromethylenepyrrolidine and Its Application to 3,3-Difluoroproline Dipeptide Synthesis

open access: yes, 2016
Mg-promoted defluorination of N-(p-methoxyphenyl)bis(trifluoromethyl)imine 1 gave perfluoroenamine 2, which was readily transformed to N-Cbz-2-trifluoromethyl-3,3-difluoropyrrolidine 10.
Hideki Amii (1325592)   +3 more
core   +1 more source

Synthesis and Reactions of Viton® Model Compounds [PDF]

open access: yes, 2019
Viton® gaskets and O-ring seals are common components of engines and other industrial systems due to their high thermal and chemical resistances. However, degradation of Viton® seals has been observed when they are exposed to oils containing basic or ...
LANCASHIRE, MARCUS,JOHN
core   +1 more source

Hydrogen fluoride abstraction from vicinal difluoroalkanes: reaction conditions and syn/anti-stereoselectivity

open access: yes
vic-Difluoroalkanes are as inert as monofluoroalkanes toward NaOMe in MeOH. Stronger bases, however, can perform dehydrofluorinations relatively smoothly.
Hamatani, Takeshi   +3 more
core   +1 more source

New Synthesis of 3-Fluoropyrroles

open access: yes, 2016
5-Alkoxymethyl-2-aryl-3-fluoro-1H-pyrroles and 2-aryl-3-fluoro-1H-pyrrole-5-carbaldehydes were efficiently prepared from the corresponding 2-aryl-5-(bromomethyl)-1-pyrrolines via electrophilic α,α-difluorination of the imino bond, using Selectfluor (1 ...
Guido Verniest (1599958)   +6 more
core   +1 more source

Dehydrofluorination Induced High Piezoelectric Poly(Vinylidene Fluoride) and Applications [PDF]

open access: yes, 2019
The piezoelectric effect in poly (vinylidene fluoride) (PVDF) and its copolymers allows the exchange of mechanical and electrical energy. Combined with their unique properties as soft materials, piezoelectric polymers have attracted great interest in ...
Lin, Jiajun
core  

Synthesis of 2,3,3,3-tetrafluoropropene by catalytic dehydrofluorination of 1,1,1,3,3-pentafluoropropane over Ni-Cr2O3 catalyst

open access: yes, 2015
1192-11972,3,3,3-Tetrafluoropropene (HFO-1234yf) has been synthesized from 1,1,1,3,3-pentafluoropropane (HFC-245fa) by dehydrofluorination over a series of Ni-Cr2O3 catalysts.
Wang, Yue-Juan   +5 more
core  

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