This work aims to develop a one-dimensional mathematical model for a novel multi - tubular thermally coupled reactor in the steady-state condition. The mentioned thermally coupled reactor includes the endothermic reaction of cyclohexane dehydrogenation ...
Roozbeh Ghani +2 more
doaj +1 more source
Fundamental material properties of the 2LiBH4-MgH2 reactive hydride composite for hydrogen storage: (II) Kinetic properties [PDF]
Reaction kinetic behaviour and cycling stability of the 2LiBH4-MgH2 reactive hydride composite (Li-RHC) are experimentally determined and analysed as a basis for the design and development of hydrogen storage tanks.
Capurso, Giovanni +11 more
core +7 more sources
Revisiting the hydrogen storage behavior of the Na-O-H system [PDF]
Solid-state reactions between sodium hydride and sodium hydroxide are unusual among hydride-hydroxide systems since hydrogen can be stored reversibly. In order to understand the relationship between hydrogen uptake/release properties and phase/structure ...
Gregory, Duncan H. +2 more
core +2 more sources
Coking-Resistant Sub-Nano Dehydrogenation Catalysts: PtnSnx/SiO2 (n=4, 7) [PDF]
We present a combined experimental/theoretical study of Pt$_n$/SiO$_2$ and Pt$_n$Sn$_x$/SiO$_2$ (n = 4, 7) model catalysts for the endothermic dehydrogenation of hydrocarbons, using the ethylene intermediate as a model reactant.
Alexandrova, Anastassia N +5 more
core
Ammonia borane-based nanocomposites as solid state hydrogen stores for portable power applications [PDF]
Ammonia borane (AB) based nanocomposites have been investigated with the aim of developing a promising solid-state hydrogen store that complies with the requirements of a modular polymer electrolyte membrane fuel cell (PEM FC) in a portable power pack ...
Bielewski, Marek +4 more
core +1 more source
Facile preparation of β-/γ-MgH2 nanocomposites under mild conditions and pathways to rapid dehydrogenation [PDF]
A magnesium hydride composite with enhanced hydrogen desorption kinetics can be synthesized via a simple wet chemical route by ball milling MgH2 with LiCl as an additive at room temperature followed by tetrahydrofuran (THF) treatment under an Ar ...
Gregory, Duncan +3 more
core +1 more source
Ethyl 2-[2-(4-Nitrobenzoyl)-1H-indol-3-yl]acetate
Ethyl 2-[2-(4-nitrobenzoyl)-1H-indol-3-yl]acetate was prepared in good yield and characterized by the aza-alkylation/intramolecular Michael cascade reaction of (E)-ethyl 3-[2-(tosylamino)phenyl]acrylate with 2-bromo-4′′-nitroacetophenone, followed by ...
Sunyoung Choi, Sung-Gon Kim
doaj +1 more source
THE INFLUENCE OF MOLYBDENUM AND TUNGSTEN ON THE CRM-OXIDE CATALYST REACTIVITY IN PROPANE ACTIVATION: A QUANTUM MECHANICS CALCULATION [PDF]
A quantum chemical calculation for the activation of propane across CrM-oxide (M = Cr, Mo, and W) catalysts in the dehydrogenation of propane into propylene was studied. The calculation was carried out via the use of the PM3 semi-empirical approach.
Toyese OYEGOKE +3 more
doaj +1 more source
New approach for fabrication germanene with Dirac electrons preserved: A first principle study
How to obtain germanene with Dirac electrons preserved is still an open challenge. Here we report a sandwich-dehydrogenation approach, i.e., to fabricate germanene through dehydrogenating germanane in a sandwiched structure.
Cao, Juexian, Guo, Zhi-Xin, Li, Ping
core +1 more source
Pressure Driven Alkane Dehydrogenation by Palladium Metal
Dehydrogenation of alkanes is of increasing importance in fulfilling global demand for olefins and offers a potential source of carbon‐neutral hydrogen as a co‐product. Currently commercial dehydrogenation processes occur at high‐temperatures (500–900 °C)
Mungo Frost +4 more
doaj +1 more source

