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The implementation of succinonitrile (SN)-based polymeric deep eutectic electrolytes (SN-PDEEs) in sodium metal batteries remains challenging due to the high reactivity of sodium metal, which leads to severe interfacial instability between the electrolyte and anode.
Yi-fan Zhao +3 more
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Yi-fan Zhao +3 more
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Advanced Interphases Layers for Dendrite-Free Sodium Metal Anodes
ACS Applied Materials & InterfacesSodium (Na) metal anode is considered the cornerstone of next-generation energy storage technology, owing to its high theoretical capacity and cost-effectiveness. However, the development of Na metal batteries is hindered by the instability and nonuniformity of the solid electrolyte interphase (SEI) and notorious formation of Na dendrites.
Yihong Gao +5 more
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Three-Dimensional Superlithiophilic Interphase for Dendrite-Free Lithium Metal Anodes
ACS Applied Materials & Interfaces, 2020Lithium metal is among the most promising anode candidates of high-energy-density batteries. However, the formed dendrites result in low Coulombic efficiency and serious security issues. Designing lithiophilic sites is one of the effective strategies to control Li deposition.
Yun Qiao +10 more
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Ultralow and biodegradable electrolyte additives for dendrite-free Zn anodes
Chemical CommunicationsCapryhydroxamic acid as an ultralow concentration and biodegradable electrolyte additive is developed to achieve dendrite-free Zn anodes.
Xinyu Chen +5 more
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Tuning Vertical Electrodeposition for Dendrites-Free Zinc-Ion Batteries
ACS NanoManipulating the crystallographic orientation of zinc deposition is recognized as an effective approach to address zinc dendrites and side reactions for aqueous zinc-ion batteries (ZIBs). We introduce 2-methylimidazole (Mlz) additive in zinc sulfate (ZSO) electrolyte to achieve vertical electrodeposition with preferential orientation of the (100) and ...
Jin Cao +11 more
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Solid–Liquid Electrolyte as a Nanoion Modulator for Dendrite-Free Lithium Anodes
ACS Applied Materials & Interfaces, 2018Rechargeable lithium (Li) metal batteries are considered the most promising of Li-based energy storage technologies. However, tree-like dendrite produced by irregular Li+ electrodeposition restricts it wide applications. Herein, based on a cation-microphase-regulation strategy, we create solid-liquid electrolytes (SLEs) by absorbing commercial liquid ...
Kaihua Wen +5 more
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Dendrite-Free Potassium–Oxygen Battery Based on a Liquid Alloy Anode
ACS Applied Materials & Interfaces, 2017The safety issue caused by the dendrite growth is not only a key research problem in lithium-ion batteries but also a critical concern in alkali metal (i.e., Li, Na, and K)-oxygen batteries where a solid metal is usually used as the anode. Herein, we demonstrate the first dendrite-free K-O2 battery at ambient temperature based on a liquid Na-K alloy ...
Wei Yu +9 more
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Porous Al Current Collector for Dendrite-Free Na Metal Anodes
Nano Letters, 2017Na-based batteries are proposed as promising energy storage candidates for beyond Li-ion technology due to the higher natural earth of Na metal. For its high capacity and low potential, Na metal may carve itself a niche when directly used as anodes. Similar to or even more problematic than Li, however, uneven plating/stripping of Na leads to dendrite ...
Shan Liu +5 more
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Design Strategies for Dendrite‐Free Potassium Metal Batteries
Batteries & SupercapsPotassium metal batteries (KMBs) have emerged as a promising next‐generation energy storage technology, offering superior energy density and cost‐effectiveness compared to conventional graphite‐based potassium (K)‐ion batteries. However, the practical implementation of KMBs faces significant challenges, primarily due to the high reactivity of K metal ...
Yanchang Chen +5 more
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An Armored Mixed Conductor Interphase on a Dendrite‐Free Lithium‐Metal Anode
Advanced Materials, 2018AbstractLithium‐metal electrodes have undergone a comprehensive renaissance to meet the requirements of high‐energy‐density batteries due to their lowest electrode potential and the very high theoretical capacity. Unfortunately, the unstable interface between lithium and nonaqueous electrolyte induces dendritic Li and low Coulombic efficiency during ...
Chong Yan +9 more
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