Results 151 to 160 of about 159,348 (259)

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve   +4 more
wiley   +1 more source

Design Principles for Next Generation of Small Organic Molecules for Photodynamics Therapy Revealed by Nonadiabatic Molecular Dynamics

open access: yesChemistry – A European Journal, EarlyView.
Molecular design reshapes the landscape of excited‐state relaxation. Nonadiabatic dynamics reveal how electronic structure guides population flow between competing pathways beyond static energetic arguments. ABSTRACT Nitrobenzochalcogenadiazole derivatives are emerging candidates for photodynamic therapy (PDT), yet the precise mechanisms governing ...
Vinícius N. da Rocha   +2 more
wiley   +1 more source

COVID-19 and Pregnancy: Key Findings. [PDF]

open access: yesScand J Immunol
Lima GG   +5 more
europepmc   +1 more source

Rationales for the Choice of Metals for Super‐Reduced Biological Metal Centers: Cobalt in Cobalamin Versus Nickel in F430

open access: yesChemistry – A European Journal, EarlyView.
DFT calculations on porphyrin, corrin, and corphin complexes of cobalt, rhodium, iron, manganese, or nickel, and QM/MM calculations on enzyme models, explore the factors controlling the availably of super‐reduced metal(I) states. True metal(I) states are seen in corrin only for cobalt, in corphin only for nickel, and not at all in porphyrin.
Radu‐Ioan Onija   +3 more
wiley   +1 more source

Precipitation of niobic acid from potassium niobate in sulphuric acid solution: A route to niobium oxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Graphical abstract illustrating the niobic acid precipitation process applied and the product obtained. Abstract This study investigates the precipitation of niobic acid (Nb2O5.nH2O) from potassium niobate solution with addition of sulphuric acid, and its subsequent thermal conversion into niobium oxide (Nb2O5). Thermodynamic modelling with PHREEQC and
Cássia R. Souza   +4 more
wiley   +1 more source

A mitochondrial-based prognostic score for risk stratification in acute myeloid leukemia. [PDF]

open access: yesBlood Res
Santos IC   +10 more
europepmc   +1 more source

Innovative electrospun geopolymer/zeolite/PVA composite membranes

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Proposed scheme of gas adsorption mechanisms on electrospun geopolymer/zeolite/PVA composite membranes. Abstract Innovative electrospun poly(vinyl alcohol) (PVA)–geopolymer–zeolite 13X composite membranes were successfully fabricated and systematically characterized.
Mariana Schneider   +7 more
wiley   +1 more source

Beyond hydrogen: Process design of a biogas steam reformer for Fischer–Tropsch synthesis

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
The effect of pressure and steam to carbon ratio on carbon conversion. Abstract We present an analysis of a pilot‐scale multi‐tubular biogas steam reforming reactor, part of a sustainable aviation fuel (SAF) development project in Brazil. The novelty of this work is the application of a new, validated power law kinetic model, specifically developed for
Rafael Belo Duarte   +3 more
wiley   +1 more source

SiC/Si ceramic hollow fibres: A new approach to Chlorella vulgaris biomass harvesting

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Efficient harvesting of microalgae is a critical challenge for the viability of biorefineries, requiring technologies that combine high selectivity, low cost, and scalability. The current work evaluated the performance of an asymmetric hollow fibre ceramic membrane (HF‐SiC70Si30), fabricated by phase inversion and sintered at 1250°C, in the ...
Erisson Paulo Borges Lopes   +4 more
wiley   +1 more source

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