Results 151 to 160 of about 49,445 (241)
A one‐shot Pd(II)‐catalyzed C─H activation strategy enables the rapid conversion of simple linear propiolamides into structurally diverse mono‐, di‐, and tri‐olefin‐bridged MPAEs. This cascade process orchestrates up to six sequential C–H activations in a single operation, providing streamlined access to highly conjugated architectures.
Haiyu Wang +4 more
wiley +1 more source
The Next Frontier in Vibrational Imaging: Chemically Designed Raman Probes Pass the Spectral Barrier. [PDF]
Fujioka H, Kamiya M.
europepmc +1 more source
Nitrooxylation—the installation of nitrate esters (–ONO2) has evolved from classical mixed‐acid protocols to catalytic and mechano‐, flow‐, photo‐, and electrochemical strategies. This review delineates ionic and radical manifolds for C–ONO2 bond formation, emphasizing mechanistic control, selected substrate scope, and selectivity.
Jayanta Dey, Dmitry Katayev
wiley +1 more source
Amide Hydrogen-Deuterium Exchange in Isotopically Mixed Water. [PDF]
Grimaldi A +4 more
europepmc +1 more source
N─H or O─H Bond Activation With a Bicyclic Si4 Ring Compound
The bicyclic Si4 ring compound with zwitterionic character reacts with NH3, H2O, and selected alcohols to give functionalized saturated silicon rings, siliconoid clusters with unsubstituted Si atoms, or simple 1,3‐addition products. The experimentally observed reactivity could be rationalized based on results from mechanistic calculations employing ...
Michael Quest +7 more
wiley +1 more source
Structural mass spectrometry techniques for characterisation of plant and algal proteins. [PDF]
Durant R, Živković D, Bolla JR.
europepmc +1 more source
A Cytosine‑Bulged (3+1) Hybrid G‑Quadruplex Formed by the Chicken DNA Replication Origin
The first high‐resolution structure of an OGRE‐derived G‐quadruplex from the chicken β‐globin replication origin reveals an intramolecular three‐layer (3+1) hybrid fold with a cytosine bulge and an unprecedented 5'‐outer‐quartet anti guanine, creating a distinctive surface for molecular recognition.
Yingying You +13 more
wiley +1 more source
Explaining deuterium-depleted water as a cancer therapy: a narrative review. [PDF]
Kyriakopoulos AM, Seneff S.
europepmc +1 more source
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz +6 more
wiley +1 more source
Supported nanoparticles and single-atom catalysts for the synthesis of deuterated alcohols. [PDF]
Tang JJ, Li SX, Zhou WX, Min XT, Qiao B.
europepmc +1 more source

