Results 21 to 30 of about 2,599 (210)

Crystal structure of the bifunctional enzyme phosphoribosyl isomerase A from Mycobacterium tuberculosis with bound light-controllable inhibitor. [PDF]

open access: yesActa Crystallogr F Struct Biol Commun
We have determined the crystal structure of an isomerase catalyzing two steps in histidine and tryptophan biosynthesis with a bound light‐switchable competitive inhibitor. The work explains the mode of action of the inhibitor and describes the discovery of a hitherto unknown third phosphate‐binding site of the enzyme.The enzyme phosphoribosyl isomerase
Rajendran C, Sterner R.
europepmc   +2 more sources

Ring closing reaction in diarylethene captured by femtosecond electron crystallography [PDF]

open access: yes, 2013
The photoinduced ring closing reaction in diarylethene, which serves as a modelsystem for understanding reactive crossings through conical intersections, was directly observed with atomic resolution using femtosecond electron diffraction.
Liu, Lai Chung   +15 more
core   +1 more source

Predicting photoactivity in dithienylethene crystalline solids

open access: yesIUCrJ, 2023
This commentary discusses the design of stimuli-responsive materials, specifically, light-responsive dithienylethene-based compounds. Recent progress in predicting photoactivity using a combination of theory and crystal structure landscape experiments is
Kristin M. Hutchins
doaj   +1 more source

Reversible Photoinduced Change in Molecular Ordering of Diarylethene Derivatives at a Solution−HOPG Interface

open access: yes, 2016
A diarylethene−pyrene diad and a diarylethene−pyrene−diarylethene triad were synthesized to investigate the photoinduced two-dimensional ordering change at a solution−HOPG interface. The molecular arrangements were detected by STM.
Shinobu Uemura (1878805)   +3 more
core   +2 more sources

Bistable Switching of π-Conjugation in a Dithienylethene-Bridged Luminescent Trityl Diradicaloid. [PDF]

open access: yesAngew Chem Int Ed Engl
Photoswitches that affect π‐conjugation offer a powerful strategy for external manipulation of luminescent diradicals. Dithienylethene‐linked persistent trityl diradicaloids, DTE‐TTM2 and F6‐DTE‐TTM2, exhibit bistable switching of their optical, electrochemical and magnetic properties.
Chang X   +11 more
europepmc   +2 more sources

Reversible C=N Bond Formation Controls Charge-Separation in an Aza-Diarylethene Photoswitch [PDF]

open access: yes, 2023
Diarylethene belong to the most eminent photoswitches and have been studied for many decades. They are found in virtually every field of applications and have become highly valuable molecular tools for instilling light-responsiveness into materials ...
Maximilian, Sacherer   +5 more
core   +2 more sources

Inelastic electron tunneling spectroscopy of difurylethene-based photochromic single-molecule junctions

open access: yesBeilstein Journal of Nanotechnology, 2017
Diarylethene-derived molecules alter their electronic structure upon transformation between the open and closed forms of the diarylethene core, when exposed to ultraviolet (UV) or visible light.
Youngsang Kim   +5 more
doaj   +1 more source

Quantitative Evaluation of Photoinduced Bending Speed of Diarylethene Crystals

open access: yesCrystals, 2015
We investigated photoinduced crystal bending behavior of various photochromic diarylethenes. In all the diarylethene derivatives we used in this work, the relationship between the initial photoinduced bending speed and the crystal thickness was well ...
Daichi Kitagawa   +3 more
doaj   +1 more source

A perfluorocyclopentene based diarylethene bearing two terpyridine moieties – synthesis, photochemical properties and influence of transition metal ions

open access: yesBeilstein Journal of Organic Chemistry, 2010
The synthesis of a perfluorocyclopentene based diarylethene bearing two terpyridine units is reported. Furthermore studies of the free ligand’s photochromism and investigations regarding the influence of various transition metal ions on the photochromic ...
Falk Wehmeier, Jochen Mattay
doaj   +1 more source

Photochromic diarylethene ligands featuring 2-(imidazol-2-yl)pyridine coordination site and their iron(II) complexes

open access: yesBeilstein Journal of Organic Chemistry, 2019
A new family of photochromic diarylethene-based ligands bearing a 2-(imidazol-2-yl)pyridine coordination unit has been developed. Four members of the new family have been synthesized.
Andrey G. Lvov   +5 more
doaj   +1 more source

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