Thermally Bistable Stiff Stilbene Photoswitches and Polymer Applications
Thermally stable photoswitches offer new opportunities for controlling polymer structures and functions under nonequilibrium conditions. This Personal Account highlights stiff stilbene (SS) and sterically hindered stiff stilbene (HSS) photoswitches, which combine large structural changes with exceptional thermal bistability.
Keiichi Imato
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Fluorescence switching of photochromic diarylethenes [PDF]
Fluorescence switching performance of photochromic diarylethenes has been studied. A bisbenzothienylethene having m-terphenyl substituents underwent reversible photochromic reactions in the amorphous solid state and exhibited fluorescence intensity change and shift of the emission band with the photochromic reaction.
Tsuyoshi Kawai +3 more
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Photo-induced and thermal reactions in thin films of an azobenzene derivative on Bi(111) [PDF]
Azobenzene is a prototypical molecular switch which can be interconverted with UV and visible light between a trans and a cis isomer in solution. While the ability to control their conformation with light is lost for many molecular photoswitches in the ...
Bronner, Christopher, Tegeder, Petra
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Light‐Programmable Interfaces: From Molecular Photoswitching to Adaptive Membrane Separations
This review advances an interface‐centered framework for light‐responsive membranes, linking molecular photoswitches (azobenzene (AZO), spiropyran (SP), diarylethene (DAE), donor–acceptor Stenhouse adducts (DASA), photoacid) to integration strategies in polymeric, porous, self‐assembled, and mixed‐matrix systems.
Liangliang Zhang +6 more
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Improving the Fatigue Resistance of Diarylethene Switches
When applying photochromic switches as functional units in light-responsive materials or devices, an often disregarded yet crucial property is their resistance to fatigue during photoisomerization. In the large family of diarylethene photoswitches, formation of an annulated isomer as a byproduct of the photochromic reaction turns out to prevent the ...
Martin Herder +5 more
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Photochemical investigation of a photochromic diarylethene compound that can be used as a wide range actinometer [PDF]
The photochromic diarylethene derivative 1,2-bis(5-(4-ethynylphenyl)-2-methylthiophen-3-yl)perfluorocyclopentene (1) was submitted to photochemical, thermal stability and fatigue resistance studies in acetonitrile, also to evaluate its possible ...
Ballardini, Roberto +5 more
core
Discrimination between FRET and non-FRET quenching in a photochromic CdSe quantum dot/dithienylethene dye system [PDF]
A photochromic Förster resonance energy transfer (FRET) system was employed to disentangle the fluorescence quenching mechanisms in quantum dot/photochromic dye hybrids.
Dworak, Lars +4 more
core +1 more source
Phototunable Polarization Volume Gratings Driven by Chiral Hydrazone Switches
Chiral hydrazone photoswitches incorporated into polarization volume gratings enable light‐driven, reversible modulation of optical properties. UV and blue light irradiation reversibly alter the hydrazone isomer ratio, leading to tunable diffraction efficiency and spectral response across the visible spectrum.
Artem Boichuk +4 more
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Click chemistry towards thermally reversible photochromic 4,5-bisthiazolyl-1,2,3-triazoles
Three new diarylethenes were synthesized from 1,2-bis(5-methyl-2-(4-substituted-phenyl)thiazol-4-yl)ethyne and benzyl azide through Ru(I)-catalyzed Huisgen cyclization reactions.
Chenxia Zhang +4 more
doaj +1 more source
The self‐assembly of carbon dots, which enables precise control over their macroscopic architectures and collective properties, profoundly enhances their functionality. This review systematically summarizes the field through four key aspects—morphology control, luminescence modulation, assembly mechanisms, and advanced applications—and thereby offers a
Kai Chen +5 more
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