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Trifluoromethylthiolation of Diazo Compounds through Copper Carbene Migratory Insertion
European Journal of Organic Chemistry, 2014 A strategy to introduce the SCF3 group through the Cu-I-promoted reaction of diazo compounds with the nucleophilic AgSCF3 trifluoromethylthiolation reagent was developed. Various diazo compounds were smoothly converted under mild conditions to form the C(
Xi Wang, Yujing Zhou, Guojing Ji
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Chemistry of Heterocyclic Compounds, 1974
Benzothiazole-2-diazonium tetrafluoroborate and its 6-bromo, 6-methyl, and 6-methoxy derivatives are relatively stable and have high electrophilicities. They are rapidly converted in weakly alkaline media to the corresponding anti-diazotates, from which primary nitrosoamines can be obtained by acidification.
V. V. Shaburov +2 more
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Benzothiazole-2-diazonium tetrafluoroborate and its 6-bromo, 6-methyl, and 6-methoxy derivatives are relatively stable and have high electrophilicities. They are rapidly converted in weakly alkaline media to the corresponding anti-diazotates, from which primary nitrosoamines can be obtained by acidification.
V. V. Shaburov +2 more
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Recent Developments in Pd‐Catalyzed Reactions of Diazo Compounds
European Journal of Organic Chemistry, 2011 Pd-catalyzed reactions of diazo compounds result in unique transformations that are distinct from those of traditional processes catalyzed by Rh-II or Cu-I catalysts.
Jianbo Wang
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Organometallic diazo compounds
Chemical Reviews, 1993Organometallic chemistry has traditionally, by definition, been concerned with the chemistry of metalcarbon-bonded compounds. Nevertheless, there is growing interest in metal-heteroatom bonds such 88 M-N, M-O, M-S, etc., in organometallic compounds.
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1967
Publisher Summary This chapter discusses the preparation of heterocyclic diazo compounds as a class and considers separately the individual characteristics of the various types, such as diazopyrroles, diazoindoles, 3-diazocarbazole, diazopyrazoles, diazoindazole, diazoimidazole, diazopurines, diazotriazoles, and diazotetrazole.
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Publisher Summary This chapter discusses the preparation of heterocyclic diazo compounds as a class and considers separately the individual characteristics of the various types, such as diazopyrroles, diazoindoles, 3-diazocarbazole, diazopyrazoles, diazoindazole, diazoimidazole, diazopurines, diazotriazoles, and diazotetrazole.
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A Photoenzymatic Strategy for Radical‐Mediated Stereoselective Hydroalkylation with Diazo Compounds
Angewandte Chemie - International Edition, 2023Xinyu Duan, Zhiguo Wang
exaly
Angewandte Chemie International Edition in English, 1964
Th. Severin, Apotheker J. Dahlström
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Th. Severin, Apotheker J. Dahlström
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