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Chemistry of Heterocyclic Compounds, 1974
Benzothiazole-2-diazonium tetrafluoroborate and its 6-bromo, 6-methyl, and 6-methoxy derivatives are relatively stable and have high electrophilicities. They are rapidly converted in weakly alkaline media to the corresponding anti-diazotates, from which primary nitrosoamines can be obtained by acidification.
V. V. Shaburov +2 more
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Benzothiazole-2-diazonium tetrafluoroborate and its 6-bromo, 6-methyl, and 6-methoxy derivatives are relatively stable and have high electrophilicities. They are rapidly converted in weakly alkaline media to the corresponding anti-diazotates, from which primary nitrosoamines can be obtained by acidification.
V. V. Shaburov +2 more
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Reaction of Diazo Compounds with Organoboron Compounds
Synthesis, 2013The transition-metal-free reactions of diazo compounds with organoboron compounds are reviewed. This type of reaction provides an alternative approach for the formation of C–C, C–B, and C–Si bonds. Moreover, by using tosylhydrazones as diazo compound precursors and boronic acids/esters as the boron substrates, this type of reaction becomes of practical
Jianbo Wang, Huan Li, Yan Zhang
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Organometallic diazo compounds
Chemical Reviews, 1993Organometallic chemistry has traditionally, by definition, been concerned with the chemistry of metalcarbon-bonded compounds. Nevertheless, there is growing interest in metal-heteroatom bonds such 88 M-N, M-O, M-S, etc., in organometallic compounds.
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1967
Publisher Summary This chapter discusses the preparation of heterocyclic diazo compounds as a class and considers separately the individual characteristics of the various types, such as diazopyrroles, diazoindoles, 3-diazocarbazole, diazopyrazoles, diazoindazole, diazoimidazole, diazopurines, diazotriazoles, and diazotetrazole.
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Publisher Summary This chapter discusses the preparation of heterocyclic diazo compounds as a class and considers separately the individual characteristics of the various types, such as diazopyrroles, diazoindoles, 3-diazocarbazole, diazopyrazoles, diazoindazole, diazoimidazole, diazopurines, diazotriazoles, and diazotetrazole.
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A Photoenzymatic Strategy for Radical-Mediated Stereoselective Hydroalkylation With Diazo Compounds
Angewandte Chemie - International Edition, 2023Jian Xu, Dong Cui, Xinyu Duan
exaly
Angewandte Chemie International Edition in English, 1964
Th. Severin, Apotheker J. Dahlström
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Th. Severin, Apotheker J. Dahlström
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