Results 131 to 140 of about 10,720 (256)

Hydrogen Atom Transfer Induces Photodegradation in Carbonyl‐Based Multi‐Resonance TADF Emitters

Angewandte Chemie, EarlyView.
Boosting triplet harvesting in N/C═O MR‐TADF emitters unexpectedly induces rapid photodegradation under oxygen‐free conditions. Spectroscopic studies reveal that triplet excited states trigger hydrogen‐atom transfer from solvent to the carbonyl unit, driven by triplet energetics and hydrogen electrophilicity.
Changfeng Si, Elvie F. P. Beaumont, Jenn Zi Yu Tan, Mitchell J. Demchuk, Zachary M. Hudson   +4 more
wiley   +2 more sources

Uncovering the Role of Intrinsic Magnetic Order in Oxygen Evolution Reaction Activity With Operando Spectroscopy

Advanced Energy Materials, EarlyView.
Operando magnetic spectroscopy provides insight into how intrinsic magnetic order modulates the oxygen evolution reaction on La0.67Sr${\rm La}_{0.67}{\rm Sr}$0.33MnO$_{0.33}{\rm MnO}$3$_3$ thin films. Temperature‐dependent operando FMR and ambient‐pressure XMCD suggest a correlation between activity and the emergence of ferromagnetic regions near and ...
Emma van der Minne, Silvia Mauri, Anatoliy A. Vereshchagin, Vadim Ratovskii, Ellen M. Kiens, Hemanita Sharma, Jan Behrends, Piero Torelli, Gertjan Koster, Christoph Baeumer   +9 more
wiley   +1 more source

Controlling Near‐Infrared Fluorescence‐to‐Phosphorescence Ratios and Triplet Lifetimes in Rhodium(I) Dimers via Primary and Secondary Coordination Sphere Effects

Angewandte Chemie, EarlyView.
RhI dimers with bridging aryl isocyanide and di‐phosphine ligands show NIR‐I or NIR‐II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh‐Rh interactions can be tuned by peripheral modification of the aryl isocyanide ligand, resulting in a rigid Rh2 core and improved photophysical properties ...
Vanitha R. Naina, Giacomo Morselli, Alessandro Prescimone, Daniel Häussinger, Oliver S. Wenger   +4 more
wiley   +2 more sources

Oxygen‐Driven Structural Reorganization by Trace Water Enabling Fast Li‐Ion Transport in a Pliable Solid Electrolyte

Advanced Energy Materials, EarlyView.
Trace water is acting as a constructive mediator in 2LiCl–GaF3, markedly increasing ionic conductivity while reorganizing local coordination. Hydration creates localized Li+ solvation environments and partially dissociates ion pairs, enhancing Li‐ion mobility.
Youngkyung Kim, Jae‐Seung Kim, Kwang Ho Shin, Jingyu Choi, Beom Jin Park, Jinyeong Choe, Jiwon Seo, Chanhyun Park, Jeongjae Lee, Dong‐Hwa Seo, Sung‐Kyun Jung   +10 more
wiley   +1 more source

Sustainable Carbon Fibers Enable Stable Long‐Term Lithium Metal Deposition for Prospective Zero‐Excess Lithium Metal Batteries

Advanced Energy Materials, EarlyView.
This work presents lightweight, lignin‐derived carbon fiber current collectors that enable controlled lithium deposition. Structural defects and intermediate‐sized pores stabilize pre‐nucleation quasi‐metallic lithium clusters, promoting uniform lithium plating and stripping.
Samantha L. S. Southern, Jonathon Cottom, Jana B. Fritzke, Emma N. Antonio, Zhenyu Guo, Bhavini Patel, Romain Tort, Ifan E. L. Stephens, Camilla Di Mino, Clare P. Grey, Rhodri Jervis, Emilia Olsson, Heather Au, Maria‐Magdalena Titirici   +13 more
wiley   +1 more source

Differential Pulse Voltammetry with a Reversible EE Mechanism

Portugaliae Electrochimica Acta, 2001
M M Moreno, A Molina, C Serna, M López-Tenés   +3 more
openaire   +1 more source

Compact Modeling of Volatile‐Switching Electrochemical Metallization Memory Cells by Means of the Electromotive Force

Advanced Intelligent Systems, EarlyView.
A volatile‐switching compact model of electrochemical metallization memory cells for neuromorphic architecture is developed and validated by reliable reproduction of device characterization measurements: I−V sweeps, SET kinetics, relaxation dynamics.
Rana Walied Ahmad, Solomon Amsalu Chekol, Julius Rasbach, Susanne Hoffmann‐Eifert, Stephan Menzel   +4 more
wiley   +1 more source

Polyethyleneimine-Directed In Situ Gold Deposition on Gallium Nitride Nanoparticles for Enhanced Electrochemical Detection of Erythromycin. [PDF]

Int J Mol Sci
Carp OE, Bostiog DI, Ursu EL, Mocanu RG, Marangoci NL, Tiginyanu I, Rotaru A.   +6 more
europepmc   +1 more source

One‐Step Electrodeposition of Iron Oxyhydroxide Onto 3D Porous Graphene Substrates for on Chip Asymmetric Micro‐Supercapacitors

Batteries &Supercaps, Volume 8, Issue 3, March 2025.
A micro‐supercapacitor with electrodeposited iron oxyhydroxide (FeOOH) as the negative electrode and birnessite manganese oxide (MnO2) as the positive electrode achieves a 2 V working voltage, stable cycling in an aqueous electrolyte, and high energy and power densities of 21 μWh cm‐2 and 2.5 mW cm‐2 respectively.
Filipe Braga, Gabriel Casano, Manel Sonni, Harry Finch, Vinod R. Dhanak, Marco Caffio, Laurence J. Hardwick   +6 more
wiley   +1 more source

Expression of concern: d-Penicillamine functionalized dendritic fibrous nanosilica (DFNS-DPA): synthesise and its application as an innovative advanced nanomaterial towards sensitive quantification of ractopamine. [PDF]

RSC Adv
Behyar MB, Shadjou N.
europepmc   +1 more source