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Differential pulse voltammetry at microdisk electrodes
Electrochimica Acta, 2005Expressions for reversible differential pulse (DP) voltammograms at microdisk electrodes were established from experimental results as a function of pulse electrolysis parameters. Three expressions were computed numerically, depending on the electrode radius and varying the pulse interval, tau.
Legeai, Sophie +2 more
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Evaluation of differential pulse voltammetry at carbon electrodes
Talanta, 1983The background and analytical responses of differential pulse voltammetry at carbon electrodes have been evaluated. Transient currents associated with small potential steps have been examined and are attributed mainly to redox reactions of various groups on the electrode surface.
J, Wang, B A, Freiha
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Analytical and Bioanalytical Chemistry, 2013
We report here on differential linear scan voltammetry, DLSV, that combines the working principles of linear scan voltammetry, LSV, and the numerous existing pulsed voltammetry techniques. DLSV preserves the information from continuous interrogation in voltage and high accuracy that LSV provides about electrochemical processes, and the much better ...
Disha B, Sheth, Miklós, Gratzl
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We report here on differential linear scan voltammetry, DLSV, that combines the working principles of linear scan voltammetry, LSV, and the numerous existing pulsed voltammetry techniques. DLSV preserves the information from continuous interrogation in voltage and high accuracy that LSV provides about electrochemical processes, and the much better ...
Disha B, Sheth, Miklós, Gratzl
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Differential Pulse Voltammetry on Spherical Microelectrodes
Electroanalysis, 1999A theory of differential pulse voltammetry (DPV) and polarography (DPP) of reversible redox reaction on the spherical electrode is developed. Numerical solutions for DPV peak currents and peak potentials are compared with analytical solutions obtained for DPP and satisfactory agreement is found when the period between pulses is more than five times ...
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Determination of Melphalan Using Differential Pulse Voltammetry
Analytical Letters, 1985Abstract The anodic oxidation of melphalan was studied on a glassy carbon disk electrode, either stationary or rotated, using a d.c. and a differential pulse potential program. The conditions have been found for a differential pulse voltammetric determination of the substance, with a detection limit of 1 × 10−6 mol 1 ...
Jiří Barek +2 more
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Multielement determination in biological materials by differential pulse voltammetry
Analytical Chemistry, 1985A simple and reliable multielement approach for the determination of up to eight elements in a single biological sample digest at major, minor, trace, and/or ultratrace levels has been developed. The method employs a wide range of voltammetric techniques such as polarography, cathodic stripping, anodic stripping, and adsorption voltammetry in their ...
S B, Adeloju, A M, Bond, M H, Briggs
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Differential pulse adsorptive stripping voltammetry of osmium-modified peptides
Bioelectrochemistry, 2002Complexes of osmium tetroxide with nitrogen ligands were developed and used in our laboratory as probes of the DNA structure. Here, we show that the complex of osmium tetroxide with 2,2'-bipyridine (Os,bipy) can be used for modification and electrochemical detection of proteins at neutral pH.
Sabina, Billová +2 more
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Differential Pulse Voltammetry of Nitrobenzene
ECS Meeting Abstracts, 2018Removal of nitrobenzene from water is of current interest due to its toxicity (1) as a mutagen and carcinogen. Water sample with initial known concentration of nitrobenzene (4mM) was taken and treated with adsorbent: spent tea leaves (2). After treatment with adsorbent nitrobenzene was analyzed using such electrochemical techniques (3) as ...
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Determination of cadmium by differential pulse adsorptive stripping voltammetry
Journal of Pharmaceutical and Biomedical Analysis, 2000A study of the adsorptive stripping voltammetry of cadmium on a mercury drop electrode is reported in which 2-mercapto-5-phenyl-amino-1,3,4-thiadiazole (MPATD), synthesized at home has been used as a chelating agent. The most suitable operating conditions and parameters such as buffer, pH, deposition potential, deposition time, ligand concentration ...
P, Suciu, M, Vega, L, Roman
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Differential-pulse adsorptive stripping voltammetry of chlorhexidine
The Analyst, 1991Chlorhexidine gluconate was shown to adsorb onto a hanging mercury drop electrode and to be amenable to quantification by adsorptive stripping voltammetry. A sensitivity of 1 × 10–7 mol dm–3 was easily achieved by simply immersing the electrode in a stirred solution (pH 9.7 ammonia-ammonium acetate buffer) of the drug for a fixed time (60 s), at a ...
GRATTERI, PAOLA +5 more
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