Results 161 to 170 of about 19,158 (261)

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

Chemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes, Nia Foster, Saima Ansari, Paul Kavanagh, Paul Dingwall, Peter C. Knipe   +5 more
wiley   +1 more source

Three-Dimensional Pore-Scale Numerical Study of the Impact of Operation Parameters on Ammonia-Methane Premixed Combustion in a Double-Layer Spherical Stacked Porous Medium Burner. [PDF]

ACS Omega
Li D, Tan F, Wang X, Xu J, Wang S, Li F, Zhu T, Zhu L, Wu Z, Liao M.   +9 more
europepmc   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

Chemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz, Sven Schaefer, Oksana Storcheva, Gabriele Raudaschl‐Sieber, Johannes Bitzer, Wolfgang Kleist, Klaus Köhler   +6 more
wiley   +1 more source

Damp-Heat Ageing of Resin Insulation Materials (Epoxy Resin and Phenolic Resin as Examples) and Their Effects on Flame Retardancy. [PDF]

Polymers (Basel)
Ming Y, Qiao X, Meng H, Zeng W, Xia X, Yang F, Xu K, Zhang Z, Huang C.   +8 more
europepmc   +1 more source

Ru Nanoparticle Supported by Mesoporous SiOx and Pillared Montmorillonite: Suppressing Catalyst Inhibition in Carbon Dioxide Hydrogenation

Chemistry – A European Journal, EarlyView.
Ru nanoparticles confined within mesoporous SiOx‐pillared montmorillonite exhibit exceptional performance for CO2 methanation. The catalyst maintains a high reaction rate even at elevated CO2 conversion while preserving high Ru mass–specific activity, overcoming typical inhibition by H2O and CO observed in conventional supported Ru catalysts.
Seunghwan Jung, Zimu Miao, Yasuhiro Sakamoto, Fuminao Kishimoto, Kazuhiro Takanabe   +4 more
wiley   +1 more source

Phytic Acid/ADP Interfacial Assembly for Flame Retardancy and Self-Extinguishment in Cellulose Paper. [PDF]

ACS Omega
Cui Y, Jiang H, Hu Y, Kong S, Sun C, Yin F.   +5 more
europepmc   +1 more source

Electrochemiluminescence of Heteroleptic Iridium(III) Complexes Featuring Substituted 2,4‐diphenylpyridinato Ligands

Chemistry – A European Journal, EarlyView.
Five heteroleptic iridium(III) complexes bearing cyclometalated 2,4‐diphenylpyridinato ligands were synthesized and their electrochemiluminescence (ECL) investigated. Two different coreactants were evaluated: tri‐n‐propylamine and benzoyl peroxide under anodic and cathodic potentials, respectively.
Ovini Jayawardana, El M. S. Martin, Oliver G. Stansfield, Egan H. Doeven, Carol Hua, Timothy U. Connell, Paul S. Francis   +6 more
wiley   +1 more source

Influence of Particle Size, Moisture, and Cloud Density on Wood Dust Ignition

Chemie Ingenieur Technik, EarlyView.
The ignition and combustion of particle clouds are strongly affected by particle interactions. This study uses spectroscopy to examine effects of particle size, water content, and cloud density. Results show ignition delay rises with larger size and density, whereas combustion duration depends mainly on water and density due to moisture‐driven ...
Matteo Giesen, Daniel Bernhardt, Michael Beckmann   +2 more
wiley   +1 more source

Durene conversion in a methanol‐to‐jet process: Exploring conversion at 150–350°C over different acid catalysts

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Acid catalyzed conversion of durene by isomerization, disproportionation, and transalkylation is of interest to the development of a methanol‐to‐jet process to reduce the amount of durene in the kerosene. It was of interest to determine whether durene conversion could be performed at a temperature lower than 350°C.
Aida G. Velasco Ortiz, Risha Raju, Arno de Klerk   +2 more
wiley   +1 more source

Non-Equilibrium Synthesis Methods to Create Metastable and High-Entropy Nanomaterials. [PDF]

Adv Sci (Weinh)
Liu S, Dun C, Urban JJ, Swihart MT.
europepmc   +1 more source