Results 201 to 210 of about 131,197 (331)

Lewis Acid‐Triggered Spatiotemporally Controllable Ring Opening in a Classic Rhodamine Featuring Φ = 95% Emission

open access: yesSmall Science, EarlyView.
This work reports a breakthrough in rhodamine activation via an elegant Lewis acid coordination strategy. It induces ring opening in spirolactone rhodamine TMR, generating exceptional fluorescence (quantum yields up to 95%) without destructive modifications or structural modification. The method preserves full photocontrol, reversibility, and real‐time
Quanchun Sun   +4 more
wiley   +1 more source

Advancing Single‐Walled Carbon Nanotubes toward Next‐Generation Electronic Materials: The Critical Roles of Purity and Processability

open access: yesSmall Methods, EarlyView.
Single‐walled carbon nanotubes (SWNTs) are promising for a wide range of applications. In particular, their exceptional electrical conductivity positions them as potential alternatives to traditional metal conductors. This review identifies the key mechanisms governing their conductivity within composites and proposes practical pathways for translating
Xiao Yu, Alex Adronov
wiley   +1 more source

N‐Heterocyclic Tetrylenes with a 1,1′‐Ferrocenylene Backbone and Bis(2,4,6‐triisopropylphenyl)boryl N‐Substituents

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Ferrocene‐based N‐heterocyclic tetrylenes [Fe{(η5‐C5H4)NBTrip2}2E](E = GePb; Trip = C6H2‐2,4,6‐iPr3)exhibit long EN and short BN bonds, in agreement with increased electrophilicity due to the ‐M effect of the N‐substituents, whose stericdemand prevents coordination of 4‐(dimethylamino)pyridine (DMAP) to theplumbylene PbII atom, but allows the ...
Sneha Mullassery   +3 more
wiley   +1 more source

Combustion Performance of Silicone Rubber Polymer Insulation Material Under Damp‐Heat Ageing Conditions: Molecular Insights Into the Effects of Structural Changes on Macroscopic Properties

open access: yesHigh Voltage, EarlyView.
ABSTRACT Silicone rubber (SR), an organic silicon polymer material, is known for its excellent heat resistance and mechanical properties. It is widely used in composite insulators and cable accessory materials. However, the ageing caused by humidity and heat significantly impacts its performance, an issue that cannot be ignored. This paper investigates
Wenyu Ye   +6 more
wiley   +1 more source

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