Results 171 to 180 of about 105,161 (275)

Impacts of Fluorination at the Ortho‐Position of Carboxy Groups on Tetrakis(biphenyl)ethene‐Based Hydrogen‐Bonded Framework

open access: yesSmall, EarlyView.
This work provides new findings on the effect of fluorination on the substitution of TPE derivatives and the modulation of the structure and fluorescence properties of hydrogen‐bonded organic framework (HOF) of F‐CBPE. ABSTRACT Fluorination of building block molecules is one of the effective engineering approaches to modulate molecular assembly in ...
Takuto Fujii   +8 more
wiley   +1 more source

Lithium Ion‐Conducting Triazacoronene‐Based Neutral 2D Covalent Organic Framework as a Solid‐State Electrolyte

open access: yesSmall, EarlyView.
A new 2D COF based on hexamethoxy triazacoronene (HMTAC) exhibits impressive ionic conductivity (10−4 S/cm), activation energy (0.25 eV), Li+ transference number (0.57), as well as promising specific capacity of 181 mAh/g with >99% Coulombic efficiency when employed as a solid‐state electrolyte in a Li || Li+@HMTAC‐COF1 || LiFePO4 cells, outperforming ...
Jonathan L. Cromer   +7 more
wiley   +1 more source

A novel water‐soluble near‐infrared fluorescent probe for monitoring viscosity fluctuations in plants and zebrafish under abiotic stresses

open access: yesSmart Molecules, EarlyView.
HJA‐MQ‐D exhibits a rapid and sensitive response to viscosity changes based on the twisted intramolecular charge transfer mechanism. Displaying near‐infrared emission and excellent water‐solubility, enabling imaging at the cellular and whole plant level.
Yixue Feng   +9 more
wiley   +1 more source

New Insights into Intersystem Crossing in Substituted Aromatics: Singlet-Triplet Conversion in Carbonyl-Substituted Anthracenes. [PDF]

open access: yesJ Phys Chem B
Guarin CA   +6 more
europepmc   +1 more source

Carbon monoxide‐triggered near‐infrared photoacoustic‐fluorescent integrated visualization tool for auxiliary diagnosis of heart failure and evaluation of reversal drug efficacy

open access: yesSmart Molecules, EarlyView.
An activatable metal‐free probe CS‐CO enables the first non‐invasive photoacoustic/fluorescence visualization of carbon monoxide (CO) fluctuations during heart failure and its reversal, linking CO levels directly to disease status. Abstract Heart failure (HF), a major global health challenge with high morbidity and mortality, lacks effective biomarkers
Hongze He   +7 more
wiley   +1 more source

Unlocking n‐alk‐1‐ynes conformers: Quantum “trigger finger” versus “stiff joint” conformations

open access: yesSmart Molecules, EarlyView.
Quantum chemical analysis reveals the unique function of n‐alk‐1‐yne terminus as a Quantum “Trigger Finger,” exhibiting two near‐isoenergetic conformers (Cs ${\mathrm{C}}_{s}$and C1 ${\mathrm{C}}_{1}$) locked by a symmetric high barrier. This contrasts with the lower asymmetric barrier of the conventional asymmetric “Stiff Joint” alkyl chain.
Ioan Bâldea
wiley   +1 more source

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