In lignin peroxidase and versatile peroxidase, low FRET from buried Trp to heme promotes long‐range electron transfer (LRET) from substrate to heme. This efficient electron flow is facilitated by reduced FRET competition. This mechanism likely evolved to enable the effective degradation of bulky, high‐redox‐potential lignin that cannot reach the enzyme'
Yi Ren +6 more
wiley +1 more source
Density Functional Theory Analysis of Luteolin Molecular Structure and Spectrum. [PDF]
Zheng Y, Zhang Y, Wang Z, Zhang Y.
europepmc +1 more source
Emergence of Continents Stabilized the Bioavailability of Boron
ABSTRACT Boron is an essential element for the development of life on Earth; borates stabilize ribose in prebiotic reactions and facilitate metabolism in higher plants. There is, however, a relatively narrow surface boron concentration range over which borates stabilize and serve as a micronutrient rather than a toxin.
Brendan V. Dyck, Jon Wade
wiley +1 more source
Effects of Donor Rigidity on Coumarin Delayed Emission: New Tricks from Old Materials. [PDF]
Paredis S +10 more
europepmc +1 more source
Sulfone-functionalized stereoisomeric [3]radialene displays guest induced modulation of porous frameworks and critical crystallization-induced near-infrared emission. [PDF]
Xu G +10 more
europepmc +1 more source
Stimuli‐Responsive Poly(Disulfide)s: A Versatile Platform for Intelligent Drug Delivery Systems
Ring‐opening polymerization based on dynamic disulfide bond exchange is an important method for synthesizing poly(disulfide)s. These polymers possess stimulus‐responsive mechanisms and show broad prospects in intelligent drug delivery. This review systematically discusses the ring‐opening polymerization strategy and research progress of drug delivery ...
Yuechen He +7 more
wiley +1 more source
Research on the Structure of the Tetrahydrofuran Complex of 2,4,6-Trinitro-3-Hydroxypyridine Silver. [PDF]
Zhang X +6 more
europepmc +1 more source
Exploring and Targeting the Connection of Iron and Copper Homeostasis to Neurodegenerative Diseases
Iron and copper dyshomeostasis, along with their interactions with key intrinsically disordered proteins (e.g., Aβ, tau, α‐synuclein) have a strong implication in the onset and progression of neurodegenerative diseases, including Alzheimer's disease (AD), Parkinson's disease (PD), Prion diseases (PrDs), Huntington's disease (HD), Wilson's disease (WD),
Xin Liu +9 more
wiley +1 more source
Counting particles in cryo-electron microscopy may result in incorrect population estimates. [PDF]
Evans L +5 more
europepmc +1 more source
Two new thiophene–pyrazole derivatives, 8a and 8b, were synthesized from thiophene 3 precursor and fully characterized. The structure of 8a was confirmed by single‐crystal X‐ray diffraction, which revealed a nonplanar conformation stabilized by NH···O hydrogen bonding and weak intermolecular contacts.
Abdullatif Bin Muhsinah +3 more
wiley +1 more source

