Results 41 to 50 of about 454 (180)

Heterogeneous PdAg alloy catalyst for selective methylation of aromatic amines with formic acid under an additive-free and solvothermal one-pot condition [PDF]

open access: yes, 2015
The methylation of amines for the synthesis of methylamines and dimethylamines as platform chemicals has been attempted mostly by homogeneous catalysts with acid additives.
Hwang, YH   +8 more
core   +1 more source

Metal Polyphenol Network Enables Photo‐ATRP Under Blue Light

open access: yesMacromolecular Rapid Communications, EarlyView.
A new ligand for light‐mediated ATRP derived from a model polyphenol was modified via a Mannich reaction to form a complex with an iron‐based photocatalyst. Experiments confirmed the formation of chain‐extendable macroinitiators, as well as fractions of polymers incapable of chain extension.
Yongkang Pang   +6 more
wiley   +1 more source

Analysis of Carbohydrates and Glycoconjugates by Matrix‐Assisted Laser Desorption/Ionization Mass Spectrometry: An Update for 2023–2024

open access: yesMass Spectrometry Reviews, EarlyView.
ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley   +1 more source

A novel n‐type dimer dopant for semiconducting polymers

open access: yesPolymer International, EarlyView.
A novel molecular n‐type dopant (1) with superior capacity to dope conjugated polymers is introduced. After charge transfer the product (2) remains in the polymer. Abstract Efficient and stable doping of organic semiconductors is crucial for adjusting their electrical properties.
Andreas Opitz   +4 more
wiley   +1 more source

High performance liquid chromatography for direct and indirect enantiomeric separations of chiral drugs [PDF]

open access: yes, 1992
This thesis deals with some analytical and pharmaceutical problems associated with chiral drugs. Although there can be marked differences between enantiomers in their pharmacological profile, many chiral drugs are still marketed as racemic mixtures.
Witte, Dirk Theodoor
core   +4 more sources

Enhanced Degradation of Vinyl Copolymers Based on Lipoic Acid

open access: yesJournal of Polymer Science, Volume 63, Issue 6, Page 1345-1351, 15 March 2025.
ABSTRACT The introduction of degradable units into the backbone of commodity vinyl polymers represents a major opportunity to address the societal challenge of plastic waste and polymer recycling. Previously, we reported the facile copolymerization of α‐lipoic acid derivatives containing 1,2‐dithiolane rings with vinyl monomers leading to the ...
Yoichi Okayama   +7 more
wiley   +1 more source

Emerging organic X‐ray scintillators enabled by thermally activated delayed fluorescence

open access: yesResponsive Materials, EarlyView.
Thermally activated delayed fluorescence (TADF) X‐ray scintillators are emerging as promising organic radiation‐conversion materials whose absorption, excited‐state dynamics, condensed‐phase organization, and screen architecture jointly govern imaging performance.
Pan Liu   +4 more
wiley   +1 more source

Metal‐Catalyzed Benzannulation: Recent Advances in Catalyst Design, Mechanistic Insights, and Aromatic Framework Construction

open access: yesThe Chemical Record, EarlyView.
This review offers a contemporary overview of metal‐catalyzed benzannulation (2018–present) encompassing transition, main‐group, post‐transition, and rare‐earth‐metal catalysts. It systematically highlights catalyst design, mechanistic insights, stereo‐ and regioselectivity, and synthetic applications toward aromatic and heteroaromatic scaffolds, while
Sana Jamshaid   +5 more
wiley   +1 more source

Access to drug metabolites via C-H functionalization: Copper-catalyzed aerobic oxidation of N,N-dimethylalkylamines in complex pharmaceuticals

open access: yes, 2014
We aim the power of C-H bond functionalization at a problem of major practical consequence-namely, scalable access to drug metabolites and their analogs.
Sames, Dalibor, Genovino, Julien
core   +1 more source

Synthesis and Plant Growth Retardant Activity of Trialkylammonium Iodides containing an Aromatic Ether Moiety

open access: yes, 1991
Department of Chemistry. Panjab Agricultural University, Ludhiana-141 004 Manuscript received 15 November 1990, accebted 7 March 1991 N,N-Diethylamines (5, 6) are prepared by treating the phenols (1, 2) with ethylene bromide in the presence of sodium ...
M. L. SHARMA   +3 more
core   +1 more source

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