Results 121 to 130 of about 27,339 (259)

Rich‐Electronic Interface Promoting Hydrogen‐Bond Reversible Formation for Ultra‐Stable and Energy‐Efficient Catalytic CO2 Capture

open access: yesCarbon Energy, EarlyView.
Bridging micro–macro scales, a biomass‐derived Ni@C interface creates electron‐rich sites and hydrogen‐bond proton‐relay pathways, tuning interfacial charge and reversible hydrogen bond to enhance carbon capture capacity. Verified by in situ spectroscopy, multi‐scale simulations, and long‐term industrial testing, this system enables low‐temperature and
Yuetong Zhao   +14 more
wiley   +1 more source

Tunable Molecular Photonic Wires via Geometric Control of Excitonically Coupled Cyanine Dimer Relays. [PDF]

open access: yesJ Phys Chem C Nanomater Interfaces
Meares AA   +11 more
europepmc   +1 more source

Enzymatic Electrosynthesis for Sustainable CO2 Conversion: Advancing Circular Carbon Economy

open access: yesCarbon Energy, EarlyView.
Enzymatic electrosynthesis (EES) offers molecular precision in synthesizing value‐added products from CO2. We highlight its distinct edge over alternative enzyme‐hybrid systems and analyze electron transfer pathways. Key strategies to overcome electron transfer bottlenecks and expand product diversity are addressed, and also data‐driven approaches for ...
Yan Xie   +7 more
wiley   +1 more source

Formic‐Acid In Situ Hydrogen Enables Programmable Ru–Pd–Pt/C Trimetallic Interfaces for Durable Acidic HER

open access: yesCarbon Energy, EarlyView.
Bamboo diaphragm−derived carbon is used as a support to prepare Ru–Pd–Pt/C catalysts through a stepwise reduction strategy. The Ru–Pd interface promotes formic acid activation and induces Pt deposition. The metallic interface of Ru–Pd–Pt/C enables H* generation, transfer, and recombination, thereby improving Pt utilization, acidic HER activity, and PEM
Liangmeng Ni   +3 more
wiley   +1 more source

A Low‐Oxidation‐State Mechanism for O─O Bond Formation in Photosystem II via Oxo–Hydroxyl Radical Coupling

open access: yesChemistry – A European Journal, EarlyView.
An oxo–hydroxyl radical coupling mechanism is identified for O─O bond formation in Photosystem II within the low‐oxidation‐state paradigm. Ca‐bound W3 forms Ox in the S4 state and subsequently couples with O5. The resulting hydroperoxide intermediate provides a mechanistic explanation for the poor resolution of Ox in XFEL structures.
Alireza Ariafard   +2 more
wiley   +1 more source

10<sup>-21</sup>-Level optical frequency dissemination over 2067 km of noise-loaded field-deployed fiber network. [PDF]

open access: yesLight Sci Appl
Chen FX   +11 more
europepmc   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

open access: yesEcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

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