Results 101 to 110 of about 1,393,038 (281)

Exploring the Catalytic Activity of Ge(II) and Sn(II) Cationic Crown Ether Complexes: Hydrosilylation

open access: yesChemistry – A European Journal, EarlyView.
Easily synthesized [Ge([12]crown‐4)2][OTf]2 catalyzes the hydrosilylation of aldehydes to give reductively coupled ethers via a carbonyl‐activated reaction pathway. The mechanism proceeds through two distinct steps: hydrosilylation followed by etherification. The open coordination face of the active cationic Ge(II) catalyst facilitates the coordination
Sarah L. McOnie   +2 more
wiley   +1 more source

C‐Terminal Functionalization Methods of Amino Acids, Peptides, and Proteins

open access: yesChemistry – A European Journal, EarlyView.
C‐terminal functionalization offers powerful routes to peptide and protein diversification, yet epimerization, hydrolysis, and selectivity remain key challenges. This Review surveys enzymatic, decarboxylative, and condensation strategies, highlighting advances toward chemo‐ and regioselective, protecting‐group‐free, atom‐efficient methods applicable to
Jay Hanssens   +3 more
wiley   +1 more source

Non‐monotonic jet pinch‐off induced by droplet impact on immiscible liquids

open access: yesDroplet, EarlyView.
The graphical abstract shows the evolution of the central jet following droplet impact and summarizes the non‐monotonic dependence of the critical Weber number on the dimensionless film thickness and Ohnesorge number. Abstract Droplet impact on immiscible liquids can generate a central jet whose pinch‐off behavior plays a crucial role in many advanced ...
Shuo Wang   +5 more
wiley   +1 more source

Instability mechanism and failure characteristics of underground cavern in block system under the action of seismic waves

open access: yesDeep Underground Science and Engineering, EarlyView.
Seismic waves with tensile stress, high amplitude, and low frequency are most likely to trigger block instability and sliding. Blocks with a single sliding surface are more prone to movement than those with multiple constraints, and roof‐positioned blocks are especially vulnerable to slide.
Xiao Wang   +4 more
wiley   +1 more source

Analytical stress solution framework for lined compressed air energy storage chambers and its application to safe burial depth determination and supporting effectiveness evaluation

open access: yesDeep Underground Science and Engineering, EarlyView.
An analytical framework delivers a closed‐form stress solution for lined compressed air energy storage chambers, enabling the determination of the minimum safe burial depth. The solution quantitatively evaluates lining support effectiveness, offering a reliable tool for chamber design and optimization.
Zeyuan Sun   +3 more
wiley   +1 more source

Seismic analysis and design of tunnels within fault ground: A review

open access: yesDeep Underground Science and Engineering, EarlyView.
The research methods of seismic response of tunnels within fault ground, including field investigations, analytical solutions, physical experiments, and numerical simulations, and seismic countermeasures are discussed. The present study examines the shortcomings and limitations of the current research and design, and puts forward proposals for future ...
Xingda Wang   +6 more
wiley   +1 more source

Investigation on tunnel stability considering pipe‐roof support with transparent soil technology

open access: yesDeep Underground Science and Engineering, EarlyView.
This study integrates transparent soil technology, 3D reconstruction and numerical simulation to captures the full‐field deformation of shield tunnel instability. Results demonstrate that pipe‐roof support enhances stability via the “soil‐arching barrier effect,” effectively restraining failure wedge development by extending stress transfer paths ...
Zhi Jia   +4 more
wiley   +1 more source

The red-crowned pigeon (Ptilinopus regina) ; the purple-crowned pigeon (Ptilinopus superbus) [picture] /

open access: yes, 1934
"Habitat: Red-crowned pigeon, E. Aust. (coastal to Bellinger River. Purple-crowned pigeon, E. Aust.
Gostelow, E. E. (Ebenezer Edward), 1866-1944.
core  

Investigation on the mechanical behavior of the multiple‐layered lining structure of a water conveyance tunnel with high internal water pressure

open access: yesDeep Underground Science and Engineering, EarlyView.
This study presents large‐scale similarity model testing (geometric ratio 3.6) of an innovative multiple‐layered lining system—comprising exterior precast segments, middle self‐compacting concrete, and an interior steel pipe—for high‐pressure (0.75 MPa) water conveyance tunnels.
Ramin Asadi   +4 more
wiley   +1 more source

Clinical Application of Crown and Bridge Using a Devised Double Crown System

open access: yesThe Journal of the Kyushu Dental Society, 1992
Satoru Inanaga   +8 more
openaire   +2 more sources

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