Results 141 to 150 of about 24,589 (267)

Monitoring Redox Pathways and Performance Limitations in Lithium‐Sulfur Batteries Using In Situ 7/6Li and 33S NMR Spectroscopies

Angewandte Chemie, EarlyView.
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke, Sunita Dey, Christopher A. O’ Keefe, Jeongjae Lee, Kazuhiro Kamiguchi, Daisuke Mori, Yuri Nakayama, Clare P. Grey   +7 more
wiley   +2 more sources

Ultra‐Low‐Strain Calcium and Magnesium Ion Storage Enabled by Tunnel‐Structured MoO3 Positive Electrode

Advanced Energy Materials, EarlyView.
A hexagonal tunnel‐structured MoO3 is nanoparticulated via hydrothermal synthesis followed by ball‐milling. As a positive electrode in Ca and Mg batteries, it delivers superior capacity and structural reversibility, enabling divalent cation intercalation with minimal lattice distortion and no phase transitions.
Reona Iimura, M. D. Hashan C. Peiris, Takashi Yabu, Toshihiko Mandai, Ruijie Zhu, Akira Nasu, Saneyuki Ohno, Masaki Matsui, Itaru Honma, Manuel Smeu, Hiroaki Kobayashi   +10 more
wiley   +1 more source

Investigation Into the Electrochemical Performance of Micron‐ and Nanosized Tin in Diglyme and Carbonate Electrolytes in Sodium Ion Batteries

Advanced Energy Materials, EarlyView.
This study compares Sn particles of different sizes in NIBs using carbonate‐ and diglyme‐based electrolytes. Diglyme electrolytes enable stable cycling despite large volume changes, while carbonate electrolytes degrade rapidly, especially with nanoparticles.
Chinnasamy Murugesan, Aaron B. Naden, Paul A. Connor, A. Robert Armstrong, John T. S. Irvine   +4 more
wiley   +1 more source

Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster

Angewandte Chemie, EarlyView.
We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang, Xiao‐Wang Li, Ning‐Zheng Li, Sheng‐Gui He, Yu‐Chen Zhang, Li‐Li Xing, Donald G. Truhlar, Jia‐Bi Ma   +7 more
wiley   +2 more sources

Natural Anionic Interfacial Reconstruction for Suppressing Pitting Corrosion Enables Durable Seawater Zinc‐Ion Batteries

Advanced Energy Materials, EarlyView.
In situ electrochemically induced molecular sieve‐alginate interface layer can suppress chloride‐induced pitting corrosion, hydrogen evolution, and dendrite growth, while regulating zinc ion transport and deposition, thereby protecting the zinc anode in seawater electrolyte.
Yunpeng Zhong, Xuhuan Xiao, Xueru Shi, Haochen Li, Zeshi Li, Zhaohan Wu, Ivan P. Parkin, Guanjie He   +7 more
wiley   +1 more source

Alcohol‐Directed Carboamination of Conjugated Enynes

Angewandte Chemie, EarlyView.
The first general three‐component intermolecular Pd‐catalyzed carboamination of conjugated enynes enables the coupling of anilines and aryl triflates to produce functionalized allenic amines, utilizing a native alcohol directing group to control regioselectivity.
Helena Solé‐Àvila, Duncan K. Brownsey, Hugo Senelle, Jerome Waser   +3 more
wiley   +2 more sources

A Unifying Approach to Self‐Organizing Systems Interacting via Conservation Laws

Advanced Intelligent Discovery, EarlyView.
The article develops a unified way to model and analyze self‐organizing systems whose interactions are constrained by conservation laws. It represents physical/biological/engineered networks as graphs and builds projection operators (from incidence/cycle structure) that enforce those constraints and decompose network variables into constrained versus ...
F. Barrows, G. Zhang, S. Anand, Z. Chen, J. Lin, A. Desai, S. Martiniani, F. Caravelli   +7 more
wiley   +1 more source

Composition‐Aware Cross‐Sectional Integration for Spatial Transcriptomics

Advanced Intelligent Discovery, EarlyView.
Multi‐section spatial transcriptomics demands coherent cell‐type deconvolution, domain detection, and batch correction, yet existing pipelines treat these tasks separately. FUSION unifies them within a composition‐aware latent framework, modeling reads as cell‐type–specific topics and clustering in embedding space.
Qishi Dong, Zijian Huang, Xuanwu Wang, Zhenghui Feng, Wei Liu, Bingding Huang   +5 more
wiley   +1 more source

Artifact-free ultralow-temperature DNP-enhanced NMR of molecular assemblies at natural isotopic abundance. [PDF]

Sci Adv
Reynard-Feytis Q, Paul S, Hediger S, De Paëpe G.   +3 more
europepmc   +1 more source

Machine Learning‐Based Estimation of Experimental Artifacts and Image Quality in Fluorescence Microscopy

Advanced Intelligent Systems, Volume 7, Issue 3, March 2025.
The use of image quality metrics in combination with machine learning enables automatic image quality assessment for fluorescence microscopy images. The method can be integrated into the experimental pipeline for optical microscopy and utilized to classify artifacts in experimental images and to build quality rankings with a reference‐free approach ...
Elena Corbetta, Thomas Bocklitz
wiley   +1 more source