Rapid thiol‐maleimide addition frequently outpaces mixing, resulting in heterogeneous hydrogels. S‐nitrosothiols act as thiol‐protecting groups, allowing uniform mixing with maleimide‐functionalized polymers before gelation. Sodium thiosulfate or sodium ascorbate then regenerates thiols on demand, triggering controlled thiol‐maleimide crosslinking ...
Julian A. Serna +7 more
wiley +1 more source
Natural Product Based Hydrogels in Biomedicine: Design Strategies and Crosslinking Mechanisms. [PDF]
Zhao M +6 more
europepmc +1 more source
Atomic‐Scale Detection of Néel Vector Switching in the Single‐Layer A‐Type Antiferromagnet Cr2S3‐2D
Interfacial electron donation from graphene redistributes charge within single‐layer Cr2S3‐2D, preferentially accumulating at the lower Cr/S plane. The resulting minute magnetic imbalance lifts the equivalence of the two magnetic sublayers, enabling atomic‐resolution identification and field‐induced control of Néel‐vector states in a two‐dimensional A ...
Affan Safeer +11 more
wiley +1 more source
Preparation and Rheological Behavior of Temperature-Resistant Hydroxypropyl Guar Gum Supramolecular Hydrogels Based on Dynamic Borate Ester Bonds. [PDF]
Xing Y +8 more
europepmc +1 more source
A novel W2TiC2Tx MXene prepared through a MAX‐phase route supports sub‐nanometer Co for highly efficient alkaline hydrogen evolution. Strong Co–W interfacial interactions optimize hydrogen adsorption and catalytic activity, enabling low overpotentials of 63 mV at 10 mA cm−2, small Tafel slope of 44.3 mV dec−1, and exceptional durability at industrially
Xiaopeng Liu +15 more
wiley +1 more source
Poly(itaconic Acid) Hydrogels with Dynamic Covalent and Supramolecular Cross-Links for High and Tunable Mechanical Properties. [PDF]
Savolainen H +5 more
europepmc +1 more source
Soft Yet Tough Tanglemers Through Rapid Photopolymerization for DLP 3D Printing
Soft yet tough tanglemers are produced through low‐initiator free radical photopolymerization and translated to DLP 3D printing. Systematic control over light intensity, initiator loading, and crosslink density reveals processing windows that balance printability, elasticity, toughness, and feature fidelity. ABSTRACT Additive manufacturing of compliant
Yutong Liu +5 more
wiley +1 more source
Mechanically Robust, Self-Healable, and Cryotolerant GelMA Hydrogel for Wearable Tactile Sensors with Enhanced Durability, Lifetime, and Environmental Stability. [PDF]
Li Z +16 more
europepmc +1 more source
For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan +12 more
wiley +1 more source
Supramolecular Materials in Extreme Environments: Balancing Stability and Dynamics. [PDF]
Wang Y +5 more
europepmc +1 more source

