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Mechanical bonds and dynamic covalent bonds
Materials Chemistry Frontiers, 2020Jishan Wu and Fraser Stoddart introduce the Materials Chemistry Frontiers themed collection on mechanical bonds and dynamic covalent bonds.
Jishan Wu, J. Fraser Stoddart
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Tuning the Fluorescence in Dynamic Covalent Bonded Liquid Crystals
ACS Applied Materials & Interfaces, 2022A series of emissive liquid crystalline materials based on salicylidene derivatives is reported and investigated with respect to their thermoresponsive and mechanochromic properties. Single-crystal analysis and temperature-dependent powder X-ray diffraction measurements allowed us to correlate the intermolecular organization of the mesogens with ...
Meik Blanke +6 more
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Single Dynamic Covalent Bond Tailored Responsive Molecular Junctions
Angewandte Chemie, 2021AbstractResponsive molecular devices are one of the core units for molecular electronics, and dynamic covalent bonds (DCBs) provide the opportunity for the fabrication of responsive molecular devices. Herein we employ a single dynamic acyl hydrazone bond to fabricate tailored molecular devices using the scanning tunneling microscopy break‐junction ...
Yong Hu +8 more
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Dynamic Covalent Bonds in Polymeric Materials
Angewandte Chemie International Edition, 2019AbstractDynamic covalent bonds (DCBs) have received significant attention over the past decade. These are covalent bonds that are capable of exchanging or switching between several molecules. Particular focus has recently been on utilizing these DCBs in polymeric materials.
Progyateg Chakma, Dominik Konkolewicz
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Dynamic covalent polymers: Reorganizable polymers with dynamic covalent bonds
Progress in Polymer Science, 2009Abstract The recent research on dynamic covalent polymers is reviewed. These polymers exhibit dynamic features originating in the reversibility of dynamic covalent bonds. The main body of the review is presented in four sections: (i) utilization of dynamic covalent bonds in reactive polymer blends, (ii) ring–chain equilibrium based on dynamic ...
Takeshi Maeda +2 more
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Templated Chromophore Assembly by Dynamic Covalent Bonds
Angewandte Chemie, 2015AbstractThrough the simultaneous use of three orthogonal dynamic covalent reactions, namely disulfide, boronate, and acyl hydrazone formation, we conceived a facile and versatile protocol to spatially organize tailored chromophores, which absorb in the blue, red, and yellow regions, on a preprogrammed α‐helix peptide. This approach allowed the assembly
Rocard, Lou +3 more
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3D printable adhesive elastomers with dynamic covalent bond rearrangement
Soft Matter, 2023Soft 3D-printable adhesive elastomers with self-healing capabilities were formulated. These materials were 3D printed into complex structures and used to modify soft robots for shape-selective lifting.
Shiwanka V. Wanasinghe +9 more
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Covalent capture of dynamic hydrogen-bonded assemblies
Chemical Communications, 2000Covalent linkage of the three calix[4]arene units in hydrogen-bonded assemblies 13(DEB)6via a threefold ring closing metathesis (RCM) reaction quantitatively converts the dynamic assemblies into covalent systems (123-membered macrocycles) that can be easily characterized using MALDI-TOF MS and HPLC.
Cardullo, F. +8 more
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Switching biological functionalities of biointerfaces via dynamic covalent bonds
Journal of Materials Chemistry B, 2016We construct a stimuli responsive biointerface via a dynamic covalent bond that could switch its surface biofunctionalities on demand. The switchability is achieved via reversible attaching/detaching of aldehyde end-functionalized biomacromolecules.
Jie, Deng +5 more
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ChemistrySelect, 2022
Abstract Covalent organic frameworks (COFs) are classified as lightweight, ordered, porous organic polymeric compounds. COF‐based materials are comprised of the covalent bonds of lightweight elements, such as C, B, O, Si, and N, with structural units. They can be used in various industrial applications.
Zahra Heravifard +3 more
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Abstract Covalent organic frameworks (COFs) are classified as lightweight, ordered, porous organic polymeric compounds. COF‐based materials are comprised of the covalent bonds of lightweight elements, such as C, B, O, Si, and N, with structural units. They can be used in various industrial applications.
Zahra Heravifard +3 more
openaire +1 more source

