Results 191 to 200 of about 1,710,928 (297)

Spatial Control Over Tether‐Tunable Coordination on Palladium for Divergent Synthesis of Bicyclo[n.1.0]alkanes via Oxidative Cyclopropanation of Enynes

open access: yesAdvanced Science, EarlyView.
We have developed a Pd‐catalyzed oxidative cyclopropanation of 1,n‐enynes employing cyclic diacyl peroxides as bifunctional reagents that serve as both tether‐tunable oxidants and spatially controlled dicarboxylate anions. ABSTRACT Bicyclo[n.1.0]alkanes are highly valuable scaffolds in drug discovery and synthetic chemistry.
Ting Yuan, Lei Shi
wiley   +1 more source

Orbital Hybridization‐Mediated Decoupling of Electrocatalytic Functions for Paired CO2 Electrosynthesis

open access: yesAdvanced Science, EarlyView.
This study constructs a dual‐scale Ag‐based catalyst on CeO2 nanorods via a facet‐guided strategy. This catalyst can induce a cascaded orbital hybridization effect, which synergistically optimizes oxygen vacancy stability, CO desorption kinetics, and charge transfer efficiency.
Youjia Wang   +6 more
wiley   +1 more source

Urea‐Formaldehyde Resin Confined Silicon Nanodots Composites: High‐Performance and Ultralong Persistent Luminescence for Dynamic AI Information Encryption

open access: yesAdvanced Science, EarlyView.
Schematic illustration of SiNDs composite materials synthesis and its internal photophysical process mechanism. And an AI‐assisted dynamic information encryption process. ABSTRACT Persistent luminescence materials typically encounter an intrinsic trade‐off between high phosphorescence quantum yield (PhQY) and ultralong phosphorescence lifetime.
Yulu Liu   +9 more
wiley   +1 more source

How AI Shapes the Future Landscape of Sustainable Building Design With Climate Change Challenges?

open access: yesAdvanced Science, EarlyView.
This review examines how artificial intelligence reshapes sustainable building design faced with climate change challenges. The authors synthesize existing studies to demonstrate AI's transformative potential across design lifecycle phases from climate‐aware form generation to performance optimization.
Pengyuan Shen   +5 more
wiley   +1 more source

Electrochemical Nitrate Reduction Reaction to Ammonia at Industrial‐Level Current Densities

open access: yesAdvanced Science, EarlyView.
This review starts from the mechanism and theoretical basis of electrochemical nitrate reduction reaction (NO3−RR), and systematically summarizes and discusses the design strategies of industrial‐level current density catalysts. In addition, the progress of industrial‐level NO3−RR‐based electrolyzers, including flow reactor and membrane electrode ...
Zhijie Cui   +4 more
wiley   +1 more source

Transition Metal Compounds for Aqueous Ammonium‐Ion Batteries: Storage Mechanisms and Electrode Design

open access: yesAdvanced Science, EarlyView.
Aqueous ammonium‐ion batteries leverage hydrogen‐bond‐mediated NH4+ storage in tunable transition metal compounds. Despite progress in Mn‐, V‐, Mo‐, and W‐based compounds, 2D LDHs, and MXenes, challenges like structural instability and slow kinetics persist. Future advances require robust host design, mechanistic understanding via operando studies, and
Can Li   +6 more
wiley   +1 more source

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