Results 221 to 230 of about 171,629 (289)

Regioselective Hydration of Terpenes with Cofactor‐Independent Carotenoid 1,2‐Hydratase

open access: yesAngewandte Chemie, EarlyView.
This study reveals a highly regioselective and cofactor‐independent enzymatic approach to terpene and terpenoid hydration using a carotenoid 1,2‐hydratase from Rubrivivax gelatinosus. Beyond detailing reaction optimization strategies, an extensive substrate scope, and scale‐up potential, it explores mutagenesis and structural modeling to identify key ...
Philip Horz   +6 more
wiley   +1 more source

Totalsynthese und Strukturkorrektur von (−)‐Sodagnitin E

open access: yesAngewandte Chemie, EarlyView.
Das Malabarican‐Triterpen Sodagnitin E ist ein in verschiedenen Pilzen vorkommendes Chromogen. Die vorliegende Arbeit stellt sowohl die erste Totalsynthese von (−)‐Sodagnitin E als auch die erste Synthese eines Malabaricans überhaupt dar. Die konvergente Synthese basiert auf der Verknüpfung zweier enantioselektiv hergestellter Fragmente mittels ...
Philipp Schoch, Tanja Gaich
wiley   +1 more source

Hochgradig enantioselektive Organokatalyse mit zweizähnigen Halogenbrückendonoren

open access: yesAngewandte Chemie, Volume 137, Issue 30, July 21, 2025.
In einer Mukaiyama‐Aldol‐Modellreaktion mit allgemeinen Substraten wurden hohe Enantioselektivitäten mit einem modifizierbaren, bidentaten Iod(I)‐basierten Halogenbrücken‐Organokatalysator erreicht. Die entscheidende Rolle der Halogenbrücken wurde durch das schlechte Abschneiden des entsprechenden Wasserstoffbrückendonors und durch DFT‐Berechnungen ...
Julian Wolf   +6 more
wiley   +1 more source

Organocatalytic kinetic resolution of sulfinamides by N/O exchange. [PDF]

open access: yesNat Commun
Zou X   +6 more
europepmc   +1 more source

On‐Surface Synthesis and Characterization of Cumulene‐Linked Stone‐Wales Polymers

open access: yesAngewandte Chemie, EarlyView.
On‐surface synthesis of one‐dimensional polymers featuring Stone‐Wales defects and cumulene linkages is demonstrated via thermally and light‐induced reactions on Au(111). STM, nc‐AFM, and Raman spectroscopy, complemented by theory calculations, reveal their chemical structure with a non‐planar geometry, and a distinct electronic bandgap of 1.8 eV ...
Elena Pérez‐Elvira   +15 more
wiley   +1 more source

Modulating effects of environmental enrichment on stress-induced changes in the gut microbiome. [PDF]

open access: yesBrain Behav Immun Health
Smith KB   +7 more
europepmc   +1 more source

Aspen-EE: An Agent-Based Model of Infrastructure Interdependency

open access: green, 2000
David Barton   +4 more
openalex   +2 more sources

Chiral Selenium‐Integrated Multi‐Resonant Thermally Activated Delayed Fluorescent Emitters Showing Improved Reverse Intersystem Crossing Rate

open access: yesAngewandte Chemie, EarlyView.
The selenium‐based tBuCz‐DiKTaSe emitter containing a twisted ortho‐disposed tert‐butylcarbazole shows high ΦPL, suppressed ACQ, fast kRISC and is chiral. The OLEDs show high EQEmax and alleviated efficiency roll‐off compared to devices with carbonyl‐based MR‐TADF emitters.
Jingxiang Wang   +9 more
wiley   +1 more source

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