Aspen-EE: An Agent-Based Model of Infrastructure Interdependency
David Barton+4 more
openalex +2 more sources
Regioselective Hydration of Terpenes with Cofactor‐Independent Carotenoid 1,2‐Hydratase
This study reveals a highly regioselective and cofactor‐independent enzymatic approach to terpene and terpenoid hydration using a carotenoid 1,2‐hydratase from Rubrivivax gelatinosus. Beyond detailing reaction optimization strategies, an extensive substrate scope, and scale‐up potential, it explores mutagenesis and structural modeling to identify key ...
Philip Horz+6 more
wiley +1 more source
Life cycle assessment of sustainable air-cured alkali-activated concrete for permeable pavements using agro-industrial wastes. [PDF]
Marathe S, Sheshadri A, Nikolaiev V.
europepmc +1 more source
Totalsynthese und Strukturkorrektur von (−)‐Sodagnitin E
Das Malabarican‐Triterpen Sodagnitin E ist ein in verschiedenen Pilzen vorkommendes Chromogen. Die vorliegende Arbeit stellt sowohl die erste Totalsynthese von (−)‐Sodagnitin E als auch die erste Synthese eines Malabaricans überhaupt dar. Die konvergente Synthese basiert auf der Verknüpfung zweier enantioselektiv hergestellter Fragmente mittels ...
Philipp Schoch, Tanja Gaich
wiley +1 more source
Arhgef7 as a key target for enriched environment rescuing spatial cognitive deficits and anxiety-like behaviors in a mouse model of Alzheimer's disease following early social isolation. [PDF]
Wang Y+10 more
europepmc +1 more source
On‐Surface Synthesis and Characterization of Cumulene‐Linked Stone‐Wales Polymers
On‐surface synthesis of one‐dimensional polymers featuring Stone‐Wales defects and cumulene linkages is demonstrated via thermally and light‐induced reactions on Au(111). STM, nc‐AFM, and Raman spectroscopy, complemented by theory calculations, reveal their chemical structure with a non‐planar geometry, and a distinct electronic bandgap of 1.8 eV ...
Elena Pérez‐Elvira+15 more
wiley +1 more source
Enantioselective Formal Synthesis of (-)-Aflatoxin B<sub>2</sub> Enabled by Pd-Catalyzed Carboetherification of 2,3-Dihydrofuran. [PDF]
Kadarauch M, Phipps RJ.
europepmc +1 more source
Engineered C–N Lyases for Stereoselective Synthesis of Tertiary Amines
EDDS lyase was subjected to iterative cycles of site‐saturation mutagenesis and screened for increased activity for the addition of 2‐((methylamino)methyl)aniline to fumarate. The final mutant, EDDS lyase CEA, accepts various N‐methyl‐1‐phenylmethanamines derivatives, yielding N,N‐disubstituted L‐aspartic acids, as well as several ortho‐substituted ...
Laura Bothof+4 more
wiley +1 more source
Ein neuartiges Konzept für katalytische asymmetrische 1,3‐dipolare Cycloadditionen mit Iminoestern verwendet modulare polyfunktionelle Lewis‐Säure‐/Azolium‐Aryloxid‐Betain‐Katalysatoren, die die endo‐ und exo‐Selektivität durch Anpassungen des Metallzentrums, des Azoliums und der Sterik steuern. DFT‐Studien zeigen eine nahezu perfekte räumliche Passung
Adrian Bürstner+13 more
wiley +1 more source