Hydrogen Bond Promoted Carbonylative Lactonization of Alkenes
A new carbonylative procedure that use tertiary alcohols containing pyridine groups and an allyl group as substates to synthesize a series of lactones has been developed. The formation of an intramolecular hydrogen bond between the pyridine group and the hydroxyl group is crucial for the transformation which enhanced the nucleophilicity of the alcohol ...
Xin Qi, Yuanrui Wang, Xiao‐Feng Wu
wiley +1 more source
TMAO accelerates cellular aging by disrupting endoplasmic reticulum integrity and mitochondrial unfolded protein response. [PDF]
Varzideh F+5 more
europepmc +1 more source
On the Facile Synthesis of Triazaarsoles Using Acyclic Precursors
Easily accessible dichloroarsanes are suitable precursors for the synthesis of novel triazaarsoles, the arsenic analogues of tetrazoles and triazaphospholes. Our findings pave the way to access and fully investigate such aromatic arsenic heterocycles in detail.
Lilian S. Szych+7 more
wiley +1 more source
Mimicking the CuD Site of pMMO via a Copper Cage‐Complex
A copper cage complex is presented that mimics the CuD site of particulate methane monooxygenase (pMMO). The CuD site has recently been proposed to be the activite site of pMMO. The cage complex presented here can catalyze aerobic oxidations of organic substrates such as benzylic alcohols to aldehydes and hydroquinones to quinones.
Shunyi Miao+3 more
wiley +1 more source
Corrigendum: Radiochemical and biological assessments of a PSMA-I&S cold kit for fast and inexpensive 99mTc-labeling for SPECT imaging and radioguided surgery in prostate cancer. [PDF]
Fuscaldi LL+11 more
europepmc +1 more source
The reported dinuclear zirconocene alkynyl methyl complex represents a multifaceted platform for the activation of small molecules. While reduction reactions furnish unusual di‐ and trinuclear hydride complexes, reactions with nitriles result in coordination and reduction of the substrate.
Hanan Al Hamwi+6 more
wiley +1 more source
Virusplot: a web server for viral integration analysis and visualization. [PDF]
Hu E+16 more
europepmc +1 more source
Pretreatment of Ru/TiO2 Catalysts Influences Activity and Selectivity in CO2 Hydrogenation
The effects of subjecting a Ru/TiO2 catalyst to reducing, oxidative, and reactive pretreatments on the activities and selectivities during CO2 hydrogenation are assessed. Pretreatment using CO/H2 syngas results in the highest activity. Pretreatment with CO2 increases the selectivity to higher hydrocarbons while O2 pretreatment results in the highest ...
Göran Baade, Robert Güttel
wiley +1 more source
NaWuReT Colloquium: Veni, Vidi, Vici? Visionary Leaders in Chemical Reaction Engineering
Discover insights from reaction engineering legends! At our 2024 Colloquium, seasoned experts shared their career challenges, strategies, and advice for the next generation. Learn how they have shaped future processes and inspired young engineers. Dive in for tips on how to make your mark!
Nils Kurig+4 more
wiley +1 more source
Unveiling the Microscopic Origin of Ion Transference Numbers in Molten Salt Systems: A Kinetic Theory Approach to an Accurate "Golden Rule". [PDF]
Gheribi AE.
europepmc +1 more source