Results 201 to 210 of about 45,469 (281)

Iron‐Mediated Electrochemical Cyclopropanation of Borodiiodomethane with Alkenes†

open access: yesChinese Journal of Chemistry, EarlyView.
This work describes an electrochemical iron‐mediated cyclopropanation of borodiiodomethane with alkenes, resulting in the formation of boro‐substituted cyclopropanes. A key feature of this study is the unexpected discovery that the cathodically generated iron ion coordinates with a biquinoline ligand in situ, facilitating the electrochemical ...
Jie Li   +3 more
wiley   +1 more source

Unveiling S‐Scheme Bi2WO6@Black‐TiO2 Heterostructure for Superior Photoelectrocatalytic Water Remediation

open access: yesCleanMat, EarlyView.
Bi2WO6@Black‐TiO2 hierarchical heterogeneous architectures are prepared via a simple hydrothermal/solvothermal strategy. An S‐Scheme carrier transfer mechanism with a solid ability to induce long‐lived electrons and holes with strong redox properties was identified via in situ x‐ray photoelectron spectroscopy and time‐resolved photoluminescence ...
Linhan Jian   +4 more
wiley   +1 more source

Remote Migratory Reductive Arylation of Unactivated Alkenes Enabled by Electrochemical Nickel Catalysis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
we have developed an electrochemical Ni−H catalyzed arylation coupling method of unactivated alkenes with aryl halides. The method displays broad functional group tolerance and proceeds under very mild conditions. Furthermore, aryl chlorides were also compatible substrates in this catalytic system. This conversion holds significant implications for the
Chao Xu, Ru‐Han A, Xiao‐Feng Wu
wiley   +1 more source

Nickelaelectro-Catalyzed C─H Activation to β-Arylated Pyrroles via Multiple Dehydrogenation. [PDF]

open access: yesAngew Chem Int Ed Engl
Okamoto K   +6 more
europepmc   +1 more source

Recent advances in boosting interfacial bubble dynamics with external fields

open access: yesDroplet, EarlyView.
External physical fields, including acoustic, magnetic, thermal, mechanical, and optical stimuli, accelerate the entire bubble‐dynamics sequence of nucleation, growth, and detachment. Abstract The efficiency of industrial electrocatalytic reactions depends not only on generating gaseous products but also on their detachment from the catalyst surface ...
Wenlu Xie   +5 more
wiley   +1 more source

Low‐Ru‐Content CuCoRu Aerogel for Boosted Electrocatalytic Nitrate Reduction to Ammonia

open access: yesEcoEnergy, EarlyView.
Low‐Ru‐content Cu5Co5Ru aerogel with enhanced hydrogenation ability and 3D robust aerogel skeletons enables high‐efficiency and long‐term electrocatalytic nitrate reduction to ammonia at low overpotential, achieving an exceptional ammonia yield rate of 2.7 ± 0.1 mmol cm−2 h−1 and a high Faradaic efficiency of ∼97% at −0.1 V versus RHE as well as an ...
Jinjie Tan   +11 more
wiley   +1 more source

AI-Accelerated Discovery of Electrocatalyst Materials. [PDF]

open access: yesACS Mater Au
Zeng Y, Wang J, Li F, Liu T, Xu A.
europepmc   +1 more source

Boosting Charge Separation in a CdIn2S4/Mo2TiC2 MXene Schottky Heterojunction for Enhanced Photocatalytic Hydrogen Production

open access: yesEcoEnergy, EarlyView.
ABSTRACT Mo2TiC2 MXene was exfoliated in situ using hydrofluoric acid solution and subsequently integrated with CdIn2S4 through physical stirring and grinding. The composite material demonstrated exceptional photocatalytic hydrogen evolution (PHE) activity without the loading of any noble metal co‐catalysts, achieving a hydrogen production rate as high
Bingzhu Li   +6 more
wiley   +1 more source

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