Results 241 to 250 of about 25,426 (293)
Convergent Valorization via Scalable C═N Bond Electrosynthesis Through Metal-Dopant Interfacial Engineering in a Flow Electrolyzer. [PDF]
Yi R +9 more
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Mediator-Enabled Co-Catalyzed <i>Z</i>‑Selective Semihydrogenation via Hydride-Free Multisite Proton-Coupled Electron Transfer. [PDF]
Parnitzke B +7 more
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A Method for Oscillation-Free Dynamic IR Compensation During Potentiostatic Electrolyses. [PDF]
Ashtaman-Pillai Syamaladevi N +5 more
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A tutorial on asymmetric electrocatalysis
Chemical Society Reviews, 2023This tutorial review delves into the unique advantages of electrochemistry in the context of asymmetric catalysis, first providing a brief tutorial introduction to electrosynthesis, then exploring representative case studies with a mechanistic focus.
Jonas Rein +3 more
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ChemPhysChem, 2006
AbstractA selection of recent theoretical and experimental studies on electrolytic hydrogen evolution is presented. It is demonstrated with well‐defined model surfaces that this reaction is a very structure‐sensitive process. Crystallographic orientation, defect density and surface composition are parameters that determine the local geometric and ...
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AbstractA selection of recent theoretical and experimental studies on electrolytic hydrogen evolution is presented. It is demonstrated with well‐defined model surfaces that this reaction is a very structure‐sensitive process. Crystallographic orientation, defect density and surface composition are parameters that determine the local geometric and ...
openaire +2 more sources
Nanoarchitectonics of Metallene Materials for Electrocatalysis
ACS Nano, 2023Controlling the synthesis of metal nanostructures is one approach for catalyst engineering and performance optimization in electrocatalysis. As an emerging class of unconventional electrocatalysts, two-dimensional (2D) metallene electrocatalysts with ultrathin sheet-like morphology have gained ever-growing attention and exhibited superior performance ...
Bo Jiang +10 more
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Insights into electrocatalysis
Phys. Chem. Chem. Phys., 2012When standard reversible potentials for bulk solution reactions, U(0), are known, the reversible potentials when the reactant and product are adsorbed on an electrocatalyst surface, U(surf)(rev), are given in terms of these potentials and the adsorption Gibbs energy bond strengths: U(surf)(rev) = U0 + D(ads)G (Ox)/F-Δ(ads)G (R)/F (i). When the Δ(ads)G (
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Adsorption Energy in Oxygen Electrocatalysis
Chemical Reviews, 2022Adsorption energy (AE) of reactive intermediate is currently the most important descriptor for electrochemical reactions (e.g., water electrolysis, hydrogen fuel cell, electrochemical nitrogen fixation, electrochemical carbon dioxide reduction, etc.), which can bridge the gap between catalyst's structure and activity.
Junming Zhang +3 more
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The Vanadium Redox Reactions – Electrocatalysis versus Non‐Electrocatalysis
ChemPhysChem, 2019AbstractCatalytic effects of surface groups on porous carbon electrodes are claimed in literature for the redox reactions V(II)/V(III) and V(IV)/V(V). The literature is critically analysed also in relation to work of this group. A method how to overcome the problem of assessing the electrochemically active surface area on porous electrodes is presented.
Ulrich Stimming +2 more
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