Results 51 to 60 of about 55,244 (327)

GeAl2‐2xFe2xO3(OH)4 Nanotubes: New Electrocatalyst for Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
Fe‐doped imogolite nanotubes are synthesized via a one‐step hydrothermal method with varying Fe substitution ratios x. Structural and spectroscopic analyses confirm homogeneous Fe incorporation while preserving tubular shape. Optimal doping at x = 0.05 enhances optical absorption, narrows band gap, reduces charge transfer resistance, and significantly ...
Yassine Naciri   +12 more
wiley   +1 more source

Research progress in photocatalysis and electrocatalysis of two-dimensional covalent organic framework materials

open access: yesCailiao gongcheng, 2023
Two-dimensional covalent organic frameworks (2D COFs) are ideal heterogeneous catalysts, and have been widely used in photocatalysis and electrocatalysis, owing to their high specific surface area, tunable porosity, facile functionalization, highly ...
ZHAO Dongdong   +6 more
doaj   +1 more source

Rapid Water Reduction to H_2 Catalyzed by a Cobalt Bis(iminopyridine) Complex [PDF]

open access: yes, 2011
A cobalt bis(iminopyridine) complex is a highly active electrocatalyst for water reduction, with an estimated apparent second order rate constant k_(app) ≤ 10^7 M^(–1)s^(–1) over a range of buffer/salt concentrations.
Gray, Harry B.   +2 more
core   +1 more source

Multi-vanadium substituted polyoxometalates as efficient electrocatalysts for the oxidation of l-cysteine at low potential on glassy carbon electrodes [PDF]

open access: yes, 2006
The electrochemical behaviours of the sandwich-type complex [As2W18(VO)3O66]11- were studied in a pH 7 medium and compared with those of the three following Dawson-type vanadium-substituted complexes: [P2V2W16O62]8- (P2V2W16), [P2MoV2W15O62]8- (P2MoV2W15)
Contant, Roland   +5 more
core   +5 more sources

Stabilizing Cationic Palladium Single‐Atom Sites on Heteroatom‐Doped Carbon for Selective Hydrogen Peroxide Electrosynthesis

open access: yesAdvanced Functional Materials, EarlyView.
In this research, it is demonstrated that dual nitrogen and sulfur doping in hollow carbon spheres creates a tunable coordination environment that stabilizes cationic Pd single atoms as robust organometallic complexes, enabling high selectivity and stability for electrochemical hydrogen peroxide production under harsh acidic and peroxide‐rich ...
Guilherme V. Fortunato   +16 more
wiley   +1 more source

Full‐Spectrum Solar Harvesting and Desalination Enabled by Supra‐Nano Amorphous Ruthenium Dioxide – Mineral Composites

open access: yesAdvanced Functional Materials, EarlyView.
A mineral‐based supra‐nano amorphous ruthenium dioxide composite (a‐Ru0.5‐AM) was designed, achieving 97% broadband solar absorption. Under one sun, it reaches 87.91 ± 0.32 °C with a distinct thermal buffering effect that favors thermal confinement.
Yunchen Long   +13 more
wiley   +1 more source

Effect of Thiols for Nitrogen Reduction to Ammonia [PDF]

open access: yes, 2019
Ammonia is an important chemical used for fertilizers and also a potential carbon-free hydrogen storage medium. The Haber-Bosch process is the main production process, which requires large energy- and capital-input. Therefore, it is crucial to develop an
Ford, Zakary R.
core   +2 more sources

Observation of Kinetic Isotope Effect in Electrocatalysis with Fully Deuterated Ultrapure Electrolytes

open access: yes, 2019
Kinetic isotope effect (KIE) is a common physicochemical effect to elucidate complicated microscopic reaction mechanism in biological, chemical and physical systems.
Sakaushi, Ken
core   +1 more source

Tailoring Microstructure in Copper‐Based Conductive Metal–Organic Frameworks for Enhanced Chemiresistive Sensing and Uptake of Sulfur Dioxide

open access: yesAdvanced Functional Materials, EarlyView.
Precursor‐ and solvent‐mediated synthesis yields four Cu3(HHTP)2 morphologies with distinct physicochemical, sorption, and sensing properties toward SO2. Uptake capacities correlate with BET surface area, while sensing performance scales with particle aspect ratio.
Patrick Damacet   +5 more
wiley   +1 more source

Substrate diffusion electrodes allow for the electrochemical hydrogenation of concentrated alkynol substrate feeds

open access: yesiScience
Summary: Electrosynthesis has the potential to revolutionize industrial organic synthesis sustainably and efficiently. However, high cell voltages and low stability often arise due to solubility issues with organic solvents, while protic electrolytes ...
Jonas Wolf   +7 more
doaj   +1 more source

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