Results 71 to 80 of about 16,523 (142)

Constructing Palladium‐Based Crystalline@Amorphous Core–Shell Heterojunctions for Efficient Formic Acid Oxidation

open access: yesAdvanced Science, EarlyView.
Crystalline@amorphous core–shell PdCN‐P nanocubes exhibit outstanding catalytic performance for formic acid oxidation, with mass activity and specific activity reaching 2.503 A mg−1Pd and 6.497 mA cm−2, respectively. Detailed theoretical and experimental analyses indicate that the unique core‐shell architecture can increase surface active sites, lower ...
Huiling Li   +8 more
wiley   +1 more source

Exploration of Oxygen Reduction Reaction Catalyzed by FePPc and Pz‐FeTPr Conjugated Organic Polymer: Insights From Grand‐Canonical Density Functional Theory

open access: yesAdvanced Science, EarlyView.
At alkaline conditions (pH = 13), for FePPc and Pz‐FeTPr at low potential (less than 0.5 V), the ORR mechanism is the *O2 mechanism (O2→∗O2→∗OOH→∗O→∗OH→H2O${{\rm{O}}_2} \to ^*{O_2} \to ^*OOH \to ^*O \to ^*OH \to {H_2}O$), Fe is the active site; for Pz‐FeTPr at high potential (larger than 0.5 V), the Fe site is covered by O2−$O_2^ - $, the nearby C site
Pengfei Yuan   +5 more
wiley   +1 more source

Nanoreactor‐Driven Uniform Nano ZnS Deposition in Tunable Porous Carbon Spheres for High‐Performance Zn‐S Batteries

open access: yesAdvanced Science, EarlyView.
In this work, a series of porous carbon spheres with tunable pore size, particle size, and shell thickness are designed as nanoreactors for the S‐ZnS redox reactions in Zn‐S batteries. The presence of abundant defects and oxygen‐containing functional groups facilitates efficient ion/electron transport throughout the reaction process, significantly ...
Yuxuan Jiang   +8 more
wiley   +1 more source

Harnessing Work Function Modulation for Hydrogen Evolution Catalysis in Mesoporous Bimetallic Pt‐M Alloys: The Role of Mesopores in Work Function Optimization

open access: yesAdvanced Science, EarlyView.
This study presents mesoporous binary Pt‐M alloy films (m‐Pt‐M, M = Pd, Rh, and Ru) with uniform porosity and tailored work functions (WFs) as an experimental study platform. The WFs of the m‐Pt‐M films exhibit a volcano‐type relationship with their HER performance.
Lei Fu   +10 more
wiley   +1 more source

Theory-oriented screening and discovery of advanced energy transformation materials in electrocatalysis

open access: yesAdvanced Powder Materials, 2021
Hongyue Jing   +5 more
semanticscholar   +1 more source

Cu─X Bonds Regulated Conduction and Polarization Loss in Conductive Metal‐Organic Framework Under Electromagnetic Field

open access: yesAdvanced Science, EarlyView.
A ligand regulation strategy by modifying functional motifs (X = −NH2, −OH, and −SH) in triphenylene is pioneered and developed to afford Cu─X bonds, achieving a synergistic conduction and polarisation loss mechanism under an electromagnetic field for enhanced electromagnetic wave absorption. Abstract Conduction and polarization are known to profoundly
Siyao Cheng   +10 more
wiley   +1 more source

Prospect of Cascade Catalysis in Magnesium‐Sulfur Batteries from Desolvation to Conversion Reactions

open access: yesAdvanced Science, EarlyView.
The dissolution and conversion reactions at the cathode interface of Mg‐S batteries are systematically summarized. This review focuses on the problems and solutions of diffusion/desolvation Mg2+ migration barrier at the sulfur/electrolyte interface as well as the current development and design of S cathodes in Mg‐S batteries under catalysis ...
Qinghua Guan   +7 more
wiley   +1 more source

Moisture Harvesting by the Structure Regulation of Hygroscopic Hydrogel for Energy and Water Sustainability

open access: yesAdvanced Electronic Materials, EarlyView.
Hygroscopic hydrogels are capable of utilizing the moisture from air, which can transfer the gaseous water to liquid by a surface phase transition. Taking advantage of this water, sustainable water production, thermal management, and electricity generation can be realized.
Yujie Du   +5 more
wiley   +1 more source

Understanding the Metal‐Center Mediated Adsorption and Redox Mechanisms in a FeMn(NbTa)2O6 Columbite Material for Anion Exchange Membrane Water Electrolyzers

open access: yesAdvanced Energy Materials, EarlyView.
FeMn(NbTa)2O6‐columbite is a sustainable and high‐performance bifunctional electrocatalyst for anion exchange membrane water electrolyzers, comparable to benchmark catalysts. In situ XAS and DFT analysis show Fe/Mn sites exhibit higher OER activity due to reduced overpotentials and favorable O→OOH energetics. The Nb/Ta sites facilitate charge transfer,
Patrick M. Bacirhonde   +17 more
wiley   +1 more source

Cerium-based nanomaterials for photo/electrocatalysis

open access: yesScience China Chemistry, 2023
Ge Li   +5 more
semanticscholar   +1 more source

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