Interfacial Water Coordination on Ruthenium Oxide Nanoparticles Confined Within Covalent Organic Framework and Its Effect on Electrochemical Nitrate Reduction. [PDF]
Li Y +6 more
europepmc +1 more source
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu +8 more
wiley +1 more source
Electronic structure modulation of Ru-NiCu bimetallic phosphide for highly efficient and stable overall water splitting in alkaline and seawater conditions. [PDF]
Du J +8 more
europepmc +1 more source
Interfacial Water‐Networks Regulate the Anodic Stability of Carbon Electrodes
The hydrogen‐bonding networks of interfacial water serve as active stability descriptors for carbon anodes: disrupted water‐networks accelerate anodic carbon corrosion, whereas strongly hydrogen‐bonded networks suppress it. This principle enables extension of the stable potential window of carbon electrodes through ionomer‐defined interfaces, as ...
Junsic Cho +12 more
wiley +1 more source
Physically mixed graphene aerogel:carbon black (GA:CB)-supported Pt or hydrothermally synthesized GA-Pt/CB hybrid electrocatalysts for PEM fuel cells. [PDF]
Teke Öner E +3 more
europepmc +1 more source
Time‐resolved in situ x‐ray absorption spectroscopy and DFTB‐based molecular dynamics simulations identify direct hydrogen atom transfer from ethanol to lattice oxygen as the elementary step of laser‐driven reduction in NiCo2O4. While this transfer is facile, the subsequent release of lattice oxygen is entropy‐driven and becomes accessible only at ...
Woo Hyeok Kim +12 more
wiley +1 more source
A cyanide-free route towards the electrosynthesis of nitriles. [PDF]
Xian J +11 more
europepmc +1 more source
Carbonate species play a previously overlooked role in near‐neutral seawater electrocatalysis. By coupling electrochemical hydrodynamics with mesoscopic simulations, we reveal a plausible carbonate‐mediated route in which carbonate functions as an interfacial proton acceptor and water as the oxygen donor, showing a possible mechanistic picture of ...
Miao Wang +2 more
wiley +1 more source
Modulated metal-support interactions for efficient nitrate electroreduction at positive potentials. [PDF]
Tang Y, Wan Y, Yan W, Zhang J, Lv R.
europepmc +1 more source
<i>N</i>-alkylated fluorographene: a metal-free electrocatalyst for the hydrogen evolution reaction. [PDF]
Shivani +7 more
europepmc +1 more source

