Results 211 to 220 of about 33,797 (295)

Coordinating Mesopore Geometry and Interfacial Water Dynamics for Iron‐Site Evolution in Nitrate Electroreduction

open access: yesAngewandte Chemie, EarlyView.
Mesopore geometry programs the working‐state interface of Fe single sites during nitrate electroreduction. Hexagonal channels reorganize interfacial water and accompany the reversible evolution of isolated Fe─O4‐like sites toward Fe─O─Fe‐like motifs, promoting successive hydrogenation toward NH3 with a Faradaic efficiency of 99.1%.
Xiangyang Liu   +8 more
wiley   +1 more source

Interfacial Water‐Networks Regulate the Anodic Stability of Carbon Electrodes

open access: yesAngewandte Chemie, EarlyView.
The hydrogen‐bonding networks of interfacial water serve as active stability descriptors for carbon anodes: disrupted water‐networks accelerate anodic carbon corrosion, whereas strongly hydrogen‐bonded networks suppress it. This principle enables extension of the stable potential window of carbon electrodes through ionomer‐defined interfaces, as ...
Junsic Cho   +12 more
wiley   +1 more source

Direct Observation of Radical‐Mediated Oxide‐to‐Alloy Transformation in Solution Under Pulsed Laser Irradiation

open access: yesAngewandte Chemie, EarlyView.
Time‐resolved in situ x‐ray absorption spectroscopy and DFTB‐based molecular dynamics simulations identify direct hydrogen atom transfer from ethanol to lattice oxygen as the elementary step of laser‐driven reduction in NiCo2O4. While this transfer is facile, the subsequent release of lattice oxygen is entropy‐driven and becomes accessible only at ...
Woo Hyeok Kim   +12 more
wiley   +1 more source

A cyanide-free route towards the electrosynthesis of nitriles. [PDF]

open access: yesNat Commun
Xian J   +11 more
europepmc   +1 more source

Rerouting Oxygen Evolution Through Interfacial Carbonate Chemistry in Near‐Neutral Seawater Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Carbonate species play a previously overlooked role in near‐neutral seawater electrocatalysis. By coupling electrochemical hydrodynamics with mesoscopic simulations, we reveal a plausible carbonate‐mediated route in which carbonate functions as an interfacial proton acceptor and water as the oxygen donor, showing a possible mechanistic picture of ...
Miao Wang   +2 more
wiley   +1 more source

<i>N</i>-alkylated fluorographene: a metal-free electrocatalyst for the hydrogen evolution reaction. [PDF]

open access: yesRSC Adv
Shivani   +7 more
europepmc   +1 more source

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