Results 61 to 70 of about 11,597 (266)

A self-reactivated PdCu catalyst for aldehyde electro-oxidation with anodic hydrogen production

Nature Communications
The low-potential aldehyde oxidation reaction can occur at low potential (~0 VRHE) and release H2 at the anode, enabling hydrogen production with less than one-tenth of the energy consumption required for water splitting.
Ming Yang, Yimin Jiang, Chung-Li Dong, Leitao Xu, Yutong Huang, Shifan Leng, Yandong Wu, Yongxiang Luo, Wei Chen, Ta Thi Thuy Nga, Shuangyin Wang, Yuqin Zou   +11 more
doaj   +1 more source

Interfacial Acid Sites‐Mediated ZnO‐Based Electrocatalysts for Sustainable Dual‐Pathway H2O2 Production and Rechargeable Zn‐H2O2 Electrochemical Cell

Advanced Materials, EarlyView.
In this work, a synergistic strategy introduces interfacial acid sites, oxygen vacancies, and built‐in electric field into ZnSe/ZnO heterojunction to optimize its electronic structure and electrode micro‐environment. This overcomes sluggish oxygen reduction reaction kinetics and low H2O2 selectivity, achieving record H2O2 productivity (754.4 M gcat−1 ...
Lijun Yang, Sitong Liu, Wencheng He, Fengzhan Sun, Shubing Bi, Hongge Pan, Lingfeng Zhu, Tianyi Ma, Lei Zhang   +8 more
wiley   +1 more source

Biomimetic Fe7S8/Carbon electrocatalyst from [FeFe]‐Hydrogenase for improving pH‐Universal electrocatalytic hydrogen production

Aggregate
Efficient and cost‐effective electrocatalysts that can operate across a wide range of pH conditions are essential for green hydrogen production. Inspired by biological systems, Fe7S8 nanoparticles incorporated on polydopamine matrix electrocatalyst were ...
Dohun Kim, Subramani Surendran, Sejin Im, Jaehyoung Lim, Kyoungsuk Jin, Ki Tae Nam, Uk Sim   +6 more
doaj   +1 more source

Engineering CO2 Reduction Pathways via Alloy‐Support Interactions in Li‐CO2 Batteries

Advanced Materials, EarlyView.
Alloy‐support interactions in RuCu/NC induce interfacial charge redistribution and shift d‐band centers, steering CO2 reduction from Li2CO3 to metastable Li2C2O4. This pathway engineering lowers the rate‐determining barrier and suppresses carbonate formation, enabling high discharge voltage (3.23 V) in Li‐CO2 batteries with reduced overpotential (0.50 ...
Liang Sun, Xindan Zhang, Guang Feng, Guoqiang Zhao, Bernt Johannessen, Guanjie Li, Shilin Zhang, Hongge Pan, Zaiping Guo   +8 more
wiley   +1 more source

Stabilized Bi(III) Sites Direct *NH2OH Pathway for Efficient Cyclohexanone Oxime Electrosynthesis

Advanced Materials, EarlyView.
The electron‐buffering effect stabilizes Bi3+ sites under electroreductive conditions, preserving a favorable interfacial water configuration that sustains the selective *NH2OH pathway and enables efficient cyclohexanone oxime electrosynthesis. ABSTRACT Coupling electrocatalytic nitrite reduction reaction (NO2−RR) with cyclohexanone conversion enables ...
Zichao Xi, Yan Du, Haijing Li, Jian Shang, Jinxiao Wu, Peng Li, Huimin Yu, Tianyi Ma, Huanyu Jin   +8 more
wiley   +1 more source

Mechanistically Interpretable Artificial Intelligence for Designing Oxygen Electrocatalysts

Advanced Materials, EarlyView.
Mechanistically interpretable artificial intelligence screens nearly seven million perovskite compositions and identifies key descriptors—d‐p hybridization and densification resistance—that govern oxygen electrocatalysis. The discovered BaCo0.8Nb0.1Zr0.1O3‐δ achieves a record 2.68 W cm−2 peak power density at 600°C with over 500 h of durable operation ...
Xueyu Hu, Yucun Zhou, Haoyu Li, Zheyu Luo, Nai Shi, Yong Ding, Weining Wang, Weilin Zhang, Doyeub Kim, Chanho Kim, Yoojin Ahn, Nikhil Govindarajan, Minda Zou, Zhijun Liu, Yuefeng Song, Meilin Liu   +15 more
wiley   +1 more source

Photocatalytic Water Splitting on the Lunar Surface: Prospects for In Situ Resource Utilization

Advanced Materials Interfaces, EarlyView.
Water has been found in craters on the moon nearby locations which are illuminated >80% of the time. Photocatalysis uses energy from sunlight to drive chemical reactions such as water splitting to produce oxygen and hydrogen. It is a scalable technology that requires lighter equipment and utilizes resources available on the moon. ABSTRACT The discovery
Ranjani Kalyan, Thomas D. Small, Gregory F. Metha, Mahmoud Adel Hamza, Thomas J. O'Dea, Yideng Shen, Cameron J. Shearer   +6 more
wiley   +1 more source

Operando X‐Ray Absorption Spectroscopy Reveals Dynamic Interfacial Metal–Metal Coordination Governing CO2 Reduction Selectivity in PdAg Alloys

Advanced Materials Interfaces, EarlyView.
Operando X‐ray absorption spectroscopy uncovers dynamic Ag–Pd coordination in PdxAg1−x electrocatalysts during CO2 reduction. Partial oxidation of Ag and composition‐dependent metal–metal bonding synergistically regulate intermediate binding, enabling ∼91% CO selectivity.
Ruspika Sundaresan, Pandiyarajan Anand, Li‐Ling Lin, Naveen Karuppusamy, Hsu‐Feng Lee, Shin‐Yu Chang, Tsu‐Hao Chang, Yu‐Cheng Shao, Ching‐Wei Tung   +8 more
wiley   +1 more source

Construction of Highly Active Pt/Ni-Fe Layered Double Hydroxide Electrocatalyst towards Methanol Oxidation in Alkaline Medium

International Journal of Electrochemical Science, 2019
A novel Pt/Ni-Fe layered double hydroxide (Pt/Ni-Fe LDH) electrocatalyst was fabricated by a two-step facile process for oxidation of methanol in alkaline medium.
Haiyan Wang, Yanan Chen, Wenfu Xie, Xiaoxue Han, Qian Feng, Rong Jiang, Hu Shang, Feifei Zhang, Linna Gao, Zonghua Wang   +9 more
doaj   +1 more source

Next‐Generation Water Treatment With Molybdenum Disulfide: Dual‐Functionality in Pollutant Adsorption and Photocatalysis

Advanced Materials Technologies, EarlyView.
ABSTRACT Molybdenum disulfide (MoS2) has attracted attention as a promising material due to the growing demand for environmentally friendly, cost‐effective, and efficient water treatment techniques. With its physicochemical characteristics, this stratified bidimensional material allows it to be highly effective in adsorption and catalytic performance ...
Pariksha Bishnoi, Gunjan Chauhan, Phil Hart, Samarjeet Singh Siwal, Vijay Kumar Thakur   +4 more
wiley   +1 more source