Microenvironment Engineering as a Design Principle for Suppressing Catalyst Metal Loss
Under ionomer‐containing microenvironments, nonporous carbon supports enhance the retention of dissolved platinum ions, whereas porous carbon supports promote pore‐confined redeposition and mitigate net platinum loss. ABSTRACT Stability losses in platinum electrocatalysts arise from dissolution, redeposition, and restructuring processes that are ...
Sumin Lim +4 more
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High-performance CeO<sub>2</sub>/rGO hybrid nanostructures as bifunctional electrocatalysts for water-splitting. [PDF]
Staline C JA +4 more
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Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du +10 more
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Dual-mode <i>in situ</i> monitoring of CO<sub>2</sub> conversion via pH indicator and UV-vis spectroscopy. [PDF]
Xie Q +8 more
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Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang +6 more
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Interface charge engineering of ternary RuCoMo oxide nanofibers toward high-current-density water electrolysis. [PDF]
Zhang L +8 more
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We report a functionalization‐mediated strategy to synthesize robust iron (Fe) atoms selectively coordinated at bridge sites on molybdenum disulfide (MoS2) nanosheets. The resulting b‐Fe‐MoS2 catalyst exhibits enhanced activity and durability for the hydrogen evolution reaction in proton exchange membrane water electrolyzers compared to atop ...
Zakaria Anfar +13 more
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Multifunctional PAA- and PEG-modified Co<sub>3</sub>V<sub>2</sub>O<sub>8</sub> nanoparticles for enhanced RhB degradation, OER activity, and antibacterial activity: experimental validation and computational insight. [PDF]
Munir A +7 more
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Ordered L12‐Pt3Mn intermetallic alloys are uniformly deposited onto atomically dispersed Mn–N–C supports. The synergistic effect between MnN4 sites and Pt3Mn elevates interfacial binding strength and dissolution barriers while favorably weakening *OH adsorption. It delivers exceptional catalytic activity and stability in fuel cells, serving as an ideal
Gongjin Chen +8 more
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Cu<sub>4</sub>SnS<sub>4</sub>-Functionalized Absorbent Pads-Derived Carbon as a Bifunctional Electrode for Supercapacitors and Hydrogen Evolution Reaction. [PDF]
Justinabraham R +4 more
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