Results 181 to 190 of about 22,278 (251)
Accelerating Materials Discovery: A Review of Machine Learning in X‐Ray Absorption Spectroscopy
Advanced Intelligent Systems, EarlyView.This review systematically details how machine learning transforms X‐ray absorption spectroscopy (XAS) analysis. It covers advanced deep learning architectures for structure‐spectra mapping and inverse tasks, while discussing key challenges like the simulation‐to‐reality gap.
Melaku Lake Tegegne +5 more
wiley +1 more source
Spin‐Polarized Interfaces Redirect CO2 Reduction From CO to Formate
Angewandte Chemie, EarlyView.The chiral electrocatalyst exploits the CISS effect to establish a spin‐polarized interface that selectively promotes formate production during CO2 reduction while effectively suppressing the competing hydrogen evolution. ABSTRACT Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO2RR) remains a critical challenge due to
Fan He +4 more
wiley +1 more source
Angewandte Chemie, EarlyView.An electron bridge strategy is developed to regulate charge polarization in Pd1 and Ni1 dual single‐atom sites, promoting CO2 reduction, nitrate reduction, and C–N coupling simultaneously. The resulting catalyst achieves efficient urea electrosynthesis with high activity and record durability over 1700 h.
Fan Wu +11 more
wiley +1 more source
Angewandte Chemie, EarlyView.Electrosynthesis of ammonia from nitrogen gas and water at ambient temperature is demonstrated using a device equipped with an electrochemical palladium membrane, which provides exclusive selectivity for the transfer of protons between the aqueous water oxidation and non‐aqueous nitrogen reduction compartments.
Ngoc‐Trung Nguyen +11 more
wiley +1 more source
Angewandte Chemie, EarlyView.Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang +8 more
wiley +1 more source
Angewandte Chemie, EarlyView.Electronegativity‐guided site differentiation is realized in a CoNiCuMoW high‐entropy alloy, where Co/Ni sites optimize hydrogen binding strength, Mo/W sites promote water dissociation, and Cu‐associated sites contribute to balanced hydrogen adsorption.
Yutong Wu +7 more
wiley +1 more source
Electro‐Organic Synthesis at a Stable Oil/Water/Solid Three‐Phase Interface Reactor
Angewandte Chemie, EarlyView.A porous membrane electrode (PME) reactor is developed to promote oil/water/solid three‐phase interfacial contact for electro‐organic synthesis. By promoting the formation of an oil/water interfacial region within or near an amphiphilic catalytic layer, the reactor enables efficient conversion of water‐insoluble organic reactants in aqueous ...
Deyin Chen +7 more
wiley +1 more source
Boosting Charge Storage in Ferri/Ferrocyanide‐Based Alkaline Redox Flow Batteries
Angewandte Chemie, EarlyView.By modifying the solvation environment, cation engineering through Li+ substitution of traditional K+ or Na+ boosts the alkaline solubility of the ferri/ferrocyanide catholyte redox couple, providing a viable pathway to overcome the long‐standing challenge of energy density limitations for aqueous redox flow batteries (RBFs).
Mahla Sarfaraz Khabbaz +6 more
wiley +1 more source
Angewandte Chemie, EarlyView.LiMn2O4${\rm LiMn}_2{\rm O}_4$ is of high interest for sustainable energy storage and conversion. Its mixed‐valence Mn3+${\rm Mn}^{3+}$/Mn4+${\text{Mn}}^{4+}$ structure drives site‐specific behavior at aqueous interfaces, featuring proton‐generating Mn4+${\text{Mn}}^{4+}$ centers and electron‐rich Mn3+${\rm Mn}^{3+}$ sites that render the surrounding ...
K. Nikolas Lausch +3 more
wiley +1 more source