Results 131 to 140 of about 49,998 (296)
Advanced screening of electrode couples [PDF]
The chromium (Cr(3+)/Cr(2+)) redox couple (electrolyte and electrode) was investigated to determine its suitability as negative electrode for the iron (Fe(3+)/Fe(2+))-chromium (Cr(3+)/Cr(2+)) redox flow battery.
Cahill, K., Giner, J. D.
core +1 more source
Advanced Science, EarlyView.An electrochemically induced transformation of polar MgO(111) into Mg(OH)2(001) creates a proton‐conductive hydroxide layer during hydrogen evolution. Operando synchrotron XRD and DFT reveal a low‐barrier Grotthuss proton‐hopping mechanism, establishing a feasible strategy for designing oxide‐hydroxide electrocatalysts with enhanced proton transport ...
Jiaying Mo +12 more
wiley +1 more source
Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production
Advanced Science, EarlyView.This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang +8 more
wiley +1 more source
Hydrophobicity Modulated Interfacial Water Distribution for Enhanced Kinetics of HER
Advanced Science, EarlyView.In electrocatalysis, hydrophilic structures improve interfacial water management by forming a continuous, compact water film that facilitates proton/hydrogen transport, thereby lowering the effective adsorption free energy of H*. By contrast, hydrophobic structures enable rapid gas transport and promote the capture and local enrichment of gaseous ...
Yucheng Dong +5 more
wiley +1 more source
O2 reduction at the IFC orbiter fuel cell O2 electrode [PDF]
O2 reduction Tafel data were obtained for the IFC Orbiter fuel cell O2 electrode (Au-10 percent Pt catalyst) at temperatures between 24 and 81 C. BET measurements gave an electrode surface area of about 2040 sq cm per sq cm of geometric area.
Fielder, William L., Singer, Joseph
core +1 more source
Advanced Science, EarlyView.A rational etching‐induced reconstruction strategy is demonstrated to fabricate one‐dimensional RuIrTe ternary nanotubes with a unique amorphous‐crystalline heterostructure. This hierarchical architecture synergistically optimizes mass transport and electronic configurations, delivering record‐breaking performance in proton exchange membrane water ...
Zhi Liang Zhao +4 more
wiley +1 more source
Advanced Science, EarlyView.Inspired by Nitrite reductase, a metal–organic framework overlayer is introduced to regulate the interfacial hydration microenvironment on Cu electrodes, enriching hydrated K+ species that act as efficient proton donors. This strategy enables nitrate‐to‐ammonia conversion with near‐unity selectivity at industrial‐level current densities in neutral ...
Yuyin Mao +4 more
wiley +1 more source
Advanced Science, EarlyView.This groundbreaking contribution to water electrolysis demonstrates that MoSe2/PANI electrocatalysts with a P–N heterojunction effectively balance the overall electrolysis reaction as the cathode, enhance anode performance, and achieve high‐efficiency, low‐energy, simultaneous hydrogen and oxygen production, revealing that the P–N heterojunction ...
Kumasser Kusse Kuchayita +2 more
wiley +1 more source
Advanced Science, EarlyView.A Cu‐mediated Ni(OH)2 catalyst with orthogonal activity by precise valence engineering simultaneously accelerates rate‐determining aldehyde C─H activation in HMF oxidation and impedes O─H deprotonation in competing OER. This multi‐functional synergistic catalysis enables FDCA production at industrial‐level current densities without sacrificing FEFDCA ...
Junge Yang +7 more
wiley +1 more source