Results 71 to 80 of about 31,784 (298)

2,2’-Dipyridylamine as Heterogeneous Organic Molecular Electrocatalyst for Two-Electron Oxygen Reduction Reaction in Acid Media [PDF]

, 2019
Continuous production of hydrogen peroxide (H2O2) through the two-electron oxygen reduction reaction (2e-ORR) in distributed electrochemical cells offers important advantages for point-of-use water treatment and pulp bleaching over the complex industrial
Xi, Yin, Ulises, Martinez, Piotr, Zelenay, Ling, Lin   +3 more
core   +2 more sources

Oxygen Evolution Electrocatalysts with Trinuclear, Mixed‐Valence Iron Motifs on Electronically Aligned Carbon Dots

Advanced Functional Materials, EarlyView.
Trinuclear iron oxo‐bridged catalytic ensembles stabilized by aspartic‐acid‐derived carbon dots provide an effective platform for alkaline oxygen evolution. Mixed‐valence charge balancing, inner‐sphere charge transport, and work‐function alignment within the N/O‐rich carbon framework promote cooperative Fe‐site chemistry and efficient OER ...
Megha A. Deshmukh, Giorgio Zoppellaro, Emiliano Fonda, Lukáš Zdražil, Shounik Paul, David Panáček, Hanuman Thorat, Zdeněk Badura, Michele Melchionna, Manuela Bevilacqua, Paolo Fornasiero, Klaus Müllen, Radek Zbořil, Aristides Bakandritsos   +13 more
wiley   +1 more source

Electrodeposited MnCu4 intermetallic compound as an efficient oxygen evolution electrocatalyst for water splitting

International Journal of Electrochemical Science
In this work it is reported the synthesis by electrodeposition of CuZn4 from alkaline solution containing citrates at pH 10. The electrodes obtained on FTO were characterized by SEM, and XRD, and these results indicate that an intermetallic compound has ...
J.C. Ballesteros, A. Gallegos-Carrillo, A. Cruz-López, S.I. Suárez-Vázquez, J. López-Tinoco, E. Valencia-Avilés   +5 more
doaj   +1 more source

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

Advanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu, Hsi‐wen Wu, Xiao Wang, Jie Zhang   +3 more
wiley   +1 more source

A self-reactivated PdCu catalyst for aldehyde electro-oxidation with anodic hydrogen production

Nature Communications
The low-potential aldehyde oxidation reaction can occur at low potential (~0 VRHE) and release H2 at the anode, enabling hydrogen production with less than one-tenth of the energy consumption required for water splitting.
Ming Yang, Yimin Jiang, Chung-Li Dong, Leitao Xu, Yutong Huang, Shifan Leng, Yandong Wu, Yongxiang Luo, Wei Chen, Ta Thi Thuy Nga, Shuangyin Wang, Yuqin Zou   +11 more
doaj   +1 more source

Structural reconstruction of electrocatalysts

Fundamental Research
Efficient and durable electrocatalysts are essential for achieving high electrocatalytic efficiency in electrocatalytic reactions, forming the bedrock of effective electrochemical energy technologies. Electrocatalysis is a complex process, marked by intricate reaction system and crucial interfacial interactions, leading to diverse degrees of ...
Chenfeng Xia, Fu-Min Li, Chaohui He, Shahid Zaman, Wei Guo, Bao Yu Xia   +5 more
openaire   +2 more sources

Phase Boundary Engineering of Co2P‐CoP Branched Nanoparticles Enhances Cobalt Oxidation for Oxygen Evolution Electrocatalysis

Advanced Materials, EarlyView.
Phase boundaries between Co2P and CoP are constructed through a controlled transformation of Co to Co2P‐CoP branched nanoparticles. The polycrystalline mixed‐phase Co2P‐CoP branches are enriched with phase boundaries that stabilize Co active sites for OER. This work highlights phase boundary engineering as a powerful approach to tailor active sites and
Zeno R. Ramadhan, Soshan Cheong, Sankhadip Saha, Qinyu Li, Xiaoran Zheng, Samuel V. Somerville, Agus R. Poerwoprajitno, Priyank V. Kumar, Liming Dai, J. Justin Gooding, Richard D. Tilley   +10 more
wiley   +1 more source

Biomimetic Fe7S8/Carbon electrocatalyst from [FeFe]‐Hydrogenase for improving pH‐Universal electrocatalytic hydrogen production

Aggregate
Efficient and cost‐effective electrocatalysts that can operate across a wide range of pH conditions are essential for green hydrogen production. Inspired by biological systems, Fe7S8 nanoparticles incorporated on polydopamine matrix electrocatalyst were ...
Dohun Kim, Subramani Surendran, Sejin Im, Jaehyoung Lim, Kyoungsuk Jin, Ki Tae Nam, Uk Sim   +6 more
doaj   +1 more source

Bimetallic Zeolitic Imidazolate Framework-derived Porous Carbon as Efficient Bifunctional Electrocatalysts for Zn-air Battery

International Journal of Electrochemical Science, 2018
The development of low-cost and efficient oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) electrocatalyst is critical for widespread application of fuel cells and metal-air batteries.
Zihan Meng, Haopeng Cai, Haolin Tang
doaj   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source