Results 181 to 190 of about 11,648 (266)

Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries

open access: yesAngewandte Chemie, EarlyView.
A proton‐switchable imine‐linked framework is developed to dynamically regulate interfacial iodine chemistry in aqueous Zn–I2 batteries, where reversible protonation/deprotonation switches the host affinity between iodide and polyiodide species. This state‐dependent regulation suppresses shuttle‐induced side reactions while preserving fast iodine redox
Feifei Wang   +14 more
wiley   +1 more source

Large-scale identical-location electron microscopy enables quantifying nanoparticulate electrocatalyst degradation

open access: yes
Kamšek AR   +8 more
europepmc   +1 more source

Linking Synthetic Materials Chemistry to Electrocatalytic Performance. [PDF]

open access: yesAngew Chem Int Ed Engl
Bagchi D   +3 more
europepmc   +1 more source

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun   +4 more
wiley   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

open access: yesAngewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du   +10 more
wiley   +1 more source

Tailoring Reconstruction of Co/Cu Mixed Oxide-Derived Tandem Electrocatalysts via <i>In Situ</i> Electrochemical Dissolution-Redeposition for Enhanced Nitrate-to-Ammonia Conversion. [PDF]

open access: yesJACS Au
G Winkler ME   +12 more
europepmc   +1 more source

Ketal Protection of Glycerol for Selective Electrosynthesis of Glyceric Acid in Highly Alkaline Media

open access: yesAngewandte Chemie, EarlyView.
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang   +6 more
wiley   +1 more source

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