Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries
A proton‐switchable imine‐linked framework is developed to dynamically regulate interfacial iodine chemistry in aqueous Zn–I2 batteries, where reversible protonation/deprotonation switches the host affinity between iodide and polyiodide species. This state‐dependent regulation suppresses shuttle‐induced side reactions while preserving fast iodine redox
Feifei Wang +14 more
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Linking Synthetic Materials Chemistry to Electrocatalytic Performance. [PDF]
Bagchi D +3 more
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Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun +4 more
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Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor. [PDF]
Kwarteng PK, Naceruddin AH, Reisner E.
europepmc +1 more source
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du +10 more
wiley +1 more source
Correction to "Iridium-Based Mixed Transition Metal Oxide (Ir<sub>3</sub>MO<sub>x</sub>, M = Ni, Co, Fe) Incorporated in the Conducting Layer as an Electrocatalyst for Boosting the Oxygen Evolution Reaction". [PDF]
europepmc +1 more source
Tailoring Reconstruction of Co/Cu Mixed Oxide-Derived Tandem Electrocatalysts via <i>In Situ</i> Electrochemical Dissolution-Redeposition for Enhanced Nitrate-to-Ammonia Conversion. [PDF]
G Winkler ME +12 more
europepmc +1 more source
Using a ketal‐protected glycerol derivative (solketal) as the oxidation substrate enables site‐selective electrooxidation that suppresses C–C cleavage on non‐noble catalysts. Highly alkaline conditions promote reactive solketal alkoxide formation, weaken the Cα─H bond to facilitate dehydrogenation, and buffer local acidification, enabling a record‐high
Jiamin Wang +6 more
wiley +1 more source
Rational Design of Ni<sup>3+</sup>-Rich Nickel Nitride Enables Paired Electrooxidation of Sterol and Hydrogen Evolution in a Flow Electrolyzer. [PDF]
Li S +11 more
europepmc +1 more source

