Results 121 to 130 of about 31,250 (195)

Interface‐Enhanced Electrochemical Epoxidation Over a Core‐Shell Nanozeolite TS‐1@Mn‐N‐C Catalyst

open access: yesAdvanced Science, EarlyView.
Core–shell interface of TS‐1@Mn‐N‐C enables in situ generation of high‐concentration H2O2 and its spatially confined activation toward epoxidation‐active η‐Ti‐OOH species, leading to highly efficient and continuous electrochemical epoxidation. The work successfully addresses the key challenge of inefficient mass transfer and slow kinetics caused by ...
Wenbiao Zhang   +7 more
wiley   +1 more source

Photocatalytic Water Oxidation on BiVO4 Sheets with Different Exposures of Crystal Facet and the Electrocatalyst as an Oxidation Co-catalyst under Visible Light Irradiation

open access: yes, 2012
Photocatalytic Water Oxidation on BiVO4 Sheets with Different Exposures of Crystal Facet and the Electrocatalyst as an Oxidation Co-catalyst under Visible Light ...
韩晶峰   +5 more
core  

Pt‐Regulated Dynamic Cu(0) Regeneration in CuPt Alloy Enables High‐Efficiency Self‐Driven Formaldehyde Fuel Cells for Potassium Formate Production

open access: yesAdvanced Science, EarlyView.
In this work, a Cu30PtX/CF anode material was synthesized to effectively catalyze the electrocatalytic formaldehyde oxidation, and thereby assembled a fuel cell that offered a high open‐circuit potential of 0.94 V and a power density of 34.3 mW cm−2. This work realizes the co‐generation of electrical energy and high‐value‐added chemicals with nearly ...
Hanxu Hou   +9 more
wiley   +1 more source

Interfacial synergetic integration of graphitic carbon nitride-polypyrrole anchored on carbon nanorod for efficient water electrolysis

open access: yesDiscover Electrochemistry
Hydrogen generation from electrolysis of water is one of the most sustainable strategies for clean energy conversion. However, the sluggish kinetics of oxygen and hydrogen evolution limit its practical implementation.
Anup Kumar Pradhan   +4 more
doaj   +1 more source

Osmium Nanoparticle Anchoring on CoFe Layered Double Hydroxides Enables High‐Valent Species Stabilization and Efficient Seawater Oxygen Evolution

open access: yesAdvanced Science, EarlyView.
Osmium nanoparticles anchored on CoFe layered double hydroxide (Os/CoFe LDH) stabilize high‐valent Co/Fe species and modulate the interfacial water configuration via surface engineering. This work presents a facile surface engineering strategy for constructing efficient and durable OER electrocatalysts for alkaline seawater, and expands the ...
Xindong She   +8 more
wiley   +1 more source

Coordination Chemistry of Single‐Atom Catalysts in Expediating Kinetics for Advanced Lithium‐Sulfur Batteries

open access: yesAdvanced Science, EarlyView.
This review elucidates the catalytic mechanisms of single‐atom catalysts (SACs) in accelerating lithium polysulfides redox kinetics. Subsequently, the modifications brought by asymmetric coordination chemistry and dual‐atom coordination structures in terms of geometric configuration engineering, molecular orbital hybridization, and interfacial charge ...
Peng Chen   +7 more
wiley   +1 more source

B‐Site Multi‐Element Micro‐Doping Engineered Air Electrodes With Fast Oxygen Kinetics for Reversible Protonic Ceramic Electrochemical Cells

open access: yesAdvanced Science, EarlyView.
Mo‐tuned multi‐element micro‐doping regulates redox chemistry, oxygen nonstoichiometry, hydration, and interfacial kinetics in PBSCF‐derived air electrodes for reversible protonic ceramic electrochemical cells. The cell with optimized PBSCFMNM03 air electrode delivers 1.10 W cm−2 in fuel cell mode and 1.88 A cm−2 at 1.3 V in electrolysis mode at 650 °C,
Wenkai Yang   +9 more
wiley   +1 more source

Magnetic‐Field‐Tuned Spin‐Dependent D‐Band and Bifunctionality in L10‐FeCoPt for Enhanced Methanol Oxidation

open access: yesAdvanced Science, EarlyView.
The d‐band center and bifunctional mechanism jointly regulate the amounts of adsorbed OH* and CO*, thereby enhancing electrocatalytic performance, while the application of an external magnetic field further boosts this performance. ABSTRACT The spin‐dependent electronic structure of transition‐metal alloys plays a key role in tuning the magnetic‐field ...
Qiqi Mo   +6 more
wiley   +1 more source

Molecular Electrocatalysis Coupled With a Palladium Membrane Reactor Affords Selective Nitrogen Reduction

open access: yesAdvanced Science, EarlyView.
A palladium membrane reactor delivers active hydrogen to homogeneous nickel terpyridine catalysts, which then selectively hydrogenate dinitrogen to ammonia. ABSTRACT Ammonia production is a cornerstone of modern industry and society, yet the conventional Haber–Bosch process accounts for nearly 2% of the global CO2 emissions. A promising and potentially
Morgan McKee   +11 more
wiley   +1 more source

Coordination‐Asymmetry‐Regulated Reconstruction of Electron‐Rich Cu Sites for pH‐Dependent Nitrate‐to‐Ammonia Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Distinct initial Cu coordination environments drive different pH‐dependent structural evolution pathways, resulting in divergent nitrate reduction activity and behavior. ABSTRACT Electrocatalytic nitrate reduction reaction (e‐NO3RR) offers a promising route to valorize nitrate‐contaminated wastewater while enabling sustainable ammonia production ...
Shih‐Ching Huang   +11 more
wiley   +1 more source

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