Results 141 to 150 of about 111,764 (351)

Epitaxial Stabilization of Ultrasmall Cu Nanoparticles With High‐Energy {110} Facets on Ti3C2 MXene for Efficient CO2‐to‐Acetate Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Cu/Ti3C2 heterostructure: Cu/Ti3C2 heterostructure achieves epitaxial stabilization of high‐energy Cu(110) facets through lattice matching and electronic interaction, enabling efficient CO2 electroreduction to acetate with 42.5% Faradaic efficiency at 235 mA·cm−2. ABSTRACT The electrochemical CO2 reduction reaction (CO2RR) to multicarbon (C2+) products
Yan‐An Li   +10 more
wiley   +1 more source

Self‐supported thin‐film electrode consisting of transition metal borides for highly efficient hydrogen evolution

open access: yesCarbon Energy
Transition metal borides (TMBs) are a new class of promising electrocatalysts for hydrogen generation by water splitting. However, the synthesis of robust all‐in‐one electrodes is challenging for practical applications.
Qi Miao   +9 more
doaj   +1 more source

The Effect of Surface Oxygen Coverage on the Oxygen Evolution Reaction over a CoFeNiCr High-Entropy Alloy

open access: yesNanomaterials
Developing cost-effective and highly active electrocatalysts for the oxygen evolution reaction (OER) is crucial for advancing sustainable energy applications.
Geng Yuan, Luis Ruiz Pestana
doaj   +1 more source

Efficient Electrocatalytic Conversion of CO2 to Pure Formic Acid Solutions via Strain‐Engineered Bismuth Nanosheets

open access: yesAdvanced Science, EarlyView.
Tensile‐strained bismuth nanosheets (TS‐BiNs) achieve a formate Faradaic efficiency of 92% at −1000 mA cm−2 and enable stable production of pure formic acid (HCOOH) in a solid‐state electrolyte reactor. Theoretical calculations reveal that the introduced strain lowers the energy barrier for *OCHO intermediate formation, fundamentally enhancing the ...
Shiqi Li   +16 more
wiley   +1 more source

Pd@Pt core-shell structured electrocatalysts for oxygen reduction in PEMFCs

open access: yes, 2013
Pd@Pt core-shell structured electrocatalysts for oxygen reduction in ...
邵志刚, 张耕
core  

Chiral‐Encoded Pt‐Ir Surfaces as Apparent Spin Filter for Enhanced Oxygen Reduction

open access: yesAdvanced Science, EarlyView.
The Chiral‐Induced Spin Selectivity (CISS) effect is employed in chiral‐encoded mesoporous Platinum‐Iridium (Pt‐Ir) electrocatalysts to enhance the oxygen reduction reaction (ORR). A break in spin symmetry leads to a substantial antagonistic difference in activity (>200%) when comparing two enantiomorphs of the same electrode.
Zikkawas Pasom   +5 more
wiley   +1 more source

Electrochemically Induced Oxide‐to‐Hydroxide Transformation Enables Fast Proton Transport for Enhanced Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
An electrochemically induced transformation of polar MgO(111) into Mg(OH)2(001) creates a proton‐conductive hydroxide layer during hydrogen evolution. Operando synchrotron XRD and DFT reveal a low‐barrier Grotthuss proton‐hopping mechanism, establishing a feasible strategy for designing oxide‐hydroxide electrocatalysts with enhanced proton transport ...
Jiaying Mo   +12 more
wiley   +1 more source

Durable hierarchical phosphorus‐doped biphase MoS2 electrocatalysts with enhanced H* adsorption

open access: yesCarbon Energy
Phase engineering is an efficient strategy for enhancing the kinetics of electrocatalytic reactions. Herein, phase engineering was employed to prepare high‐performance phosphorous‐doped biphase (1T/2H) MoS2 (P‐BMS) nanoflakes for hydrogen evolution ...
Yongteng Qian   +6 more
doaj   +1 more source

Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production

open access: yesAdvanced Science, EarlyView.
This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang   +8 more
wiley   +1 more source

Hydrophobicity Modulated Interfacial Water Distribution for Enhanced Kinetics of HER

open access: yesAdvanced Science, EarlyView.
In electrocatalysis, hydrophilic structures improve interfacial water management by forming a continuous, compact water film that facilitates proton/hydrogen transport, thereby lowering the effective adsorption free energy of H*. By contrast, hydrophobic structures enable rapid gas transport and promote the capture and local enrichment of gaseous ...
Yucheng Dong   +5 more
wiley   +1 more source

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