Results 241 to 250 of about 111,764 (351)

Wrinkled Strain‐Enriched High‐Entropy Metallene Enables Cross‐Site Tandem Nitrate‐to‐Ammonia

open access: yesAngewandte Chemie, EarlyView.
A wrinkled 2D PdFeCoNiCuIn high‐entropy metallene overcomes the low atom utilization of high‐entropy alloys. Indium‐induced strain and p‐d hybridization enable a cross‐site tandem pathway for nitrate reduction to ammonia. It achieves 99.3% Faradaic efficiency and an NH3 yield rate of 4.55 mmol h−1 mgcat−1.
Tianfang Yang   +6 more
wiley   +1 more source

Ketazine‐Linked Covalent Organic Framework for Metal‐Free Electrocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
A metal‐free fluorinated ketazine‐linked COF is introduced as an efficient electrocatalyst for nitrate reduction to ammonia under neutral conditions. Fluorine substitution enhances π–π stacking and crystallinity, enabling a Faradaic efficiency of 59.9% and an NH3 yield rate of 1639.9 µmol h−1 mgCOF−1 at −0.9 V versus RHE. This establishes an unexplored
Islam E. Khalil   +12 more
wiley   +1 more source

Engineering PtFe/LiO<sub>2</sub> Frontier Orbital Interaction in Li-O<sub>2</sub> Batteries. [PDF]

open access: yesNanomicro Lett
Zhou Y   +16 more
europepmc   +1 more source

Mesoporous N,S‐Dual‐Doped Carbon Nanoreactors via Entropy‐Driven Interface Self‐Assembly for Efficient H2O2 Electrosynthesis

open access: yesAngewandte Chemie, EarlyView.
An entropy‐driven interface self‐assembly strategy is proposed for the controllable synthesis of mesoporous N,S‐dual‐doped carbon nanoreactors. The N,S‐dual‐doping sites optimized the *OOH adsorption, boosting the 2e− selectivity, while the favorable mesostructure accelerated O2 enrichment.
Fei Liu   +6 more
wiley   +1 more source

Ordered Pt3Mn Intermetallic Nanoparticles Supported on Atomically Dispersed Mn–N–C as Electrocatalysts for Fuel Cells

open access: yesAngewandte Chemie, EarlyView.
Ordered L12‐Pt3Mn intermetallic alloys are uniformly deposited onto atomically dispersed Mn–N–C supports. The synergistic effect between MnN4 sites and Pt3Mn elevates interfacial binding strength and dissolution barriers while favorably weakening *OH adsorption. It delivers exceptional catalytic activity and stability in fuel cells, serving as an ideal
Gongjin Chen   +8 more
wiley   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

open access: yesAngewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li   +9 more
wiley   +1 more source

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